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@ARTICLE{Bluszcz:5003,
author = {Bluszcz, P. and Lücke, A. and Ohlendorf, C. and
Zolitschka, B.},
title = {{S}easonal dynamics of stable isotopes and element ratios
in authigenic calcites during their precipitation and
dissolution, {S}acrower {S}ee (northeastern {G}ermany)},
journal = {Journal of limnology},
volume = {68},
issn = {1129-5767},
address = {Verbania},
publisher = {Ist.},
reportid = {PreJuSER-5003},
pages = {257 - 273},
year = {2009},
note = {Record converted from VDB: 12.11.2012},
abstract = {The seasonal evolution of chemical and physical water
properties as well as particle fluxes was monitored in
Sacrower See (northern Germany) during two consecutive years
(Oct 2003 - Oct 2005). Additonally, we measured delta O-18
and delta C-13 as well as Sr:Ca and Mg:Ca ratios of
authigenic calcites that were collected in sequencing
sediment traps in order to disentangle environmental and
climatic factors controlling these parameters. In
particular, our aim was to find out if element ratios and
the isotopic composition of calcites reflect changes, in
water and air temperatures. Lake water is highly enriched in
O-18 (-1.3 to $-2.5\%.$ VSMOW) with an evaporative increase
of 0.6 parts per thousand during summer. Values are 5-6
parts per thousand more positive than groundwater values and
4-5 parts per thousand more positive than long-term weighted
annual means of precipitation. During spring and summer,
high amounts of dissolved phosphate cause eutrophic
conditions and calcite precipitation in isotopic
disequilibrium. Measured values are depleted in 180 by 2 to
10 parts per thousand compared to calculated equilibrium
values. Resuspension and partial dissolution of calcite in
the water column contribute to this isotopic divergence in
summer and autumn as delta O-18(ca) and delta C-13 values
increased in the hypolimnion during this time. Mg:Ca and
Sr:Ca ratios are altered by dissolution as well. In the
hypolimnion these ratios were higher than in the epilimnion.
Another reason for the huge deviation between measured and
theoretical delta O-18(ca) values during summer is the
occurrence of large amounts of Phacotus lenticularis in the
carbonate - fraction. High amounts of Phacotus lead to more
negative delta O-18(ca) and more positive delta C-13 values.
Several characteristics of delta O-18(ca) and delta C-13 are
also reflected by Mg:Ca and Sr:Ca ratios and isotopic
composition of oxygen and carbon were influenced by the
onset and stability of stratification. Especially the
earlier onset of stratification it? 2005 caused higher
sediment fluxes and more positive carbon and oxygen isotope
values of bioinduced carbonates compared to 2004.},
keywords = {J (WoSType)},
cin = {ICG-4},
ddc = {570},
cid = {I:(DE-Juel1)VDB793},
pnm = {Terrestrische Umwelt},
pid = {G:(DE-Juel1)FUEK407},
shelfmark = {Limnology},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000268778300010},
doi = {10.3274/JL09-68-2-10},
url = {https://juser.fz-juelich.de/record/5003},
}