Home > Publications database > Diastereomer-differentiating hydrolysis of 1,3-diol-acetonides : a simplified procedure for the separation of syn- and anti-1,3-diols > print

001     51092
005     20200423204326.0
024 7 _ |a pmid:11843606
|2 pmid
024 7 _ |a 10.1021/ol017223u
|2 DOI
024 7 _ |a WOS:000173885800038
|2 WOS
024 7 _ |a 2128/2448
|2 Handle
037 _ _ |a PreJuSER-51092
041 _ _ |a eng
082 _ _ |a 540
084 _ _ |2 WoS
|a Chemistry, Organic
100 1 _ |a Bode, S. E.
|0 P:(DE-Juel1)VDB7907
|b 0
|u FZJ
245 _ _ |a Diastereomer-differentiating hydrolysis of 1,3-diol-acetonides : a simplified procedure for the separation of syn- and anti-1,3-diols
260 _ _ |a Washington, DC
|b ACS
|c 2002
300 _ _ |a 619 - 621
336 7 _ |a Journal Article
|0 PUB:(DE-HGF)16
|2 PUB:(DE-HGF)
336 7 _ |a Output Types/Journal article
|2 DataCite
336 7 _ |a Journal Article
|0 0
|2 EndNote
336 7 _ |a ARTICLE
|2 BibTeX
336 7 _ |a JOURNAL_ARTICLE
|2 ORCID
336 7 _ |a article
|2 DRIVER
440 _ 0 |a Organic Letters
|x 1523-7060
|0 4749
|y 4
|v 4
500 _ _ |a Record converted from VDB: 12.11.2012
520 _ _ |a [reaction: see text] A new method to facilitate the separation of diastereomeric syn- and anti-1,3-diols is described. The method relies on the different hydrolysis rates of the corresponding diastereomeric acetonides. Treatment of a dichloromethane solution of syn- and anti-1,3-diol-acetonide with a catalytic amount of diluted aqueous hydrochloric acid leads to the selective cleavage of the anti diastereomer. The resulting anti-1,3-diol can be easily separated from the unchanged syn-1,3-diol-acetonide.
536 _ _ |a Biotechnologie
|c L02
|2 G:(DE-HGF)
|0 G:(DE-Juel1)FUEK256
|x 0
588 _ _ |a Dataset connected to Web of Science, Pubmed
650 _ 2 |2 MeSH
|a Catalysis
650 _ 2 |2 MeSH
|a Dioxanes: chemical synthesis
650 _ 2 |2 MeSH
|a Hydrolysis
650 _ 2 |2 MeSH
|a Indicators and Reagents
650 _ 2 |2 MeSH
|a Kinetics
650 _ 2 |2 MeSH
|a Stereoisomerism
650 _ 7 |0 0
|2 NLM Chemicals
|a Dioxanes
650 _ 7 |0 0
|2 NLM Chemicals
|a Indicators and Reagents
650 _ 7 |a J
|2 WoSType
700 1 _ |a Müller, M.
|0 P:(DE-Juel1)VDB1106
|b 1
|u FZJ
700 1 _ |a Wolberg, M.
|0 P:(DE-Juel1)VDB1800
|b 2
|u FZJ
773 _ _ |a 10.1021/ol017223u
|g Vol. 4, p. 619 - 621
|p 619 - 621
|q 4<619 - 621
|0 PERI:(DE-600)1501522-1
|t Organic letters
|v 4
|y 2002
|x 1523-7060
856 4 _ |u https://juser.fz-juelich.de/record/51092/files/8009.pdf
|y OpenAccess
856 4 _ |u https://juser.fz-juelich.de/record/51092/files/8009.jpg?subformat=icon-1440
|x icon-1440
|y OpenAccess
856 4 _ |u https://juser.fz-juelich.de/record/51092/files/8009.jpg?subformat=icon-180
|x icon-180
|y OpenAccess
856 4 _ |u https://juser.fz-juelich.de/record/51092/files/8009.jpg?subformat=icon-640
|x icon-640
|y OpenAccess
909 C O |o oai:juser.fz-juelich.de:51092
|p openaire
|p open_access
|p driver
|p VDB
|p dnbdelivery
913 1 _ |k L02
|v Biotechnologie
|l Biotechnologie
|b Leben
|0 G:(DE-Juel1)FUEK256
|x 0
914 1 _ |y 2002
915 _ _ |0 StatID:(DE-HGF)0010
|a JCR/ISI refereed
915 _ _ |2 StatID
|0 StatID:(DE-HGF)0510
|a OpenAccess
920 1 _ |k IBT-2
|l Biotechnologie 2
|g IBT
|z ab 31.10.10 weitergeführt IBG-1
|0 I:(DE-Juel1)VDB56
|x 0
970 _ _ |a VDB:(DE-Juel1)8009
980 _ _ |a VDB
980 _ _ |a JUWEL
980 _ _ |a ConvertedRecord
980 _ _ |a journal
980 _ _ |a I:(DE-Juel1)IBG-1-20101118
980 _ _ |a UNRESTRICTED
980 _ _ |a FullTexts
980 1 _ |a FullTexts
981 _ _ |a I:(DE-Juel1)IBG-1-20101118

LibraryCollectionCLSMajorCLSMinorLanguageAuthor
Marc 21