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000052117 041__ $$aeng
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000052117 084__ $$2WoS$$aChemistry, Organic
000052117 1001_ $$0P:(DE-Juel1)VDB12652$$aBode, S.$$b0$$uFZJ
000052117 245__ $$aStereoselective Synthesis of 1,3-diols
000052117 260__ $$aStuttgart [u.a.]$$bThieme$$c2006
000052117 300__ $$a557 - 588
000052117 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article
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000052117 440_0 $$05695$$aSynthesis: Journal of Synthetic Organic Chemistry$$v$$x0039-7881$$y4
000052117 500__ $$aRecord converted from VDB: 12.11.2012
000052117 520__ $$aMany polyketide-derived natural products contain a synor anti-1,3-diol unit. No general and simple approach exists for the flexible synthesis of polyols and other polyketide-derived structural units, therefore a multitude of methods for the stereoselective synthesis of 1,3-diols has been developed. Asymmetric homogeneous and heterogeneous hydrogenation and diastereoselective reduction, chain elongation, enzymatic and nonenzymatic desymmetrization, or dynamic kinetic resolution are some of these methods. The development of different methods to synthesize these 1,3-diols stereoselectively is important, as often small structural changes in a molecule result in low yields or low stereoselectivity with a known method. This review article highlights some of the recent developments in this field.
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000052117 65320 $$2Author$$aasymmetric synthesis
000052117 65320 $$2Author$$areductions
000052117 65320 $$2Author$$aaldol reactions
000052117 65320 $$2Author$$abiocatalysis
000052117 65320 $$2Author$$adesymmetrizations
000052117 65320 $$2Author$$aalcohols
000052117 7001_ $$0P:(DE-Juel1)VDB1800$$aWolberg, M.$$b1$$uFZJ
000052117 7001_ $$0P:(DE-Juel1)VDB1106$$aMüller, M.$$b2$$uFZJ
000052117 773__ $$0PERI:(DE-600)2033062-5$$a10.1055/s-2006-926315$$gp. 557 - 588$$p557 - 588$$q557 - 588$$tSynthesis$$x0039-7881$$y2006
000052117 8567_ $$uhttp://dx.doi.org/10.1055/s-2006-926315
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000052117 9141_ $$y2006
000052117 915__ $$0StatID:(DE-HGF)0010$$aJCR/ISI refereed
000052117 9201_ $$0I:(DE-Juel1)VDB56$$gIBT$$kIBT-2$$lBiotechnologie 2$$x0$$zab 31.10.10 weitergeführt IBG-1
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