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@ARTICLE{Bossmeyer:52213,
      author       = {Bossmeyer, J. and Brauers, T. and Richter, C. and Rohrer,
                      F. and Wegener, R. and Wahner, A.},
      title        = {{S}imulation {C}hamber {S}tudies on the {NO}3 {C}hemistry
                      of {A}tmospheric {A}ldehydes},
      journal      = {Geophysical research letters},
      volume       = {33},
      issn         = {0094-8276},
      address      = {Washington, DC},
      publisher    = {American Geophysical Union},
      reportid     = {PreJuSER-52213},
      pages        = {L18810},
      year         = {2006},
      note         = {Record converted from VDB: 12.11.2012},
      abstract     = {Absolute reaction rate studies of NO3 radicals with 4
                      aldehydes were performed in the atmosphere simulation
                      chamber SAPHIR at the Research Center Julich. Rate
                      coefficients ( ethanal: 2.6 +/- 0.5, propanal: 5.8 +/- 1.0,
                      butanal: 11.9 +/- 1.4, benzaldehyde: 2.2 +/- 0.6; in 10(-15)
                      cm(3) s(-1) at 300 K) were determined from measured
                      concentration time profiles of aldehydes and NO3 at near
                      ambient conditions. The values for the aliphatic aldehydes
                      are in good agreement with the most recent recommendations (
                      IUPAC Subcommittee on Gas Kinetic Data Evaluation for
                      Atmospheric Chemistry: Evaluated kinetic and photochemical
                      data for atmospheric chemistry, 2005, available at http://
                      www. iupac- kinetic. ch. cam. ac. uk). The measured
                      concentration- time profiles of precursor aldehydes, NO3,
                      NO2, and of product aldehydes were compared to model
                      calculations based on the MCM v3 ( Jenkin et al., 2003;
                      Saunders et al., 2003). Differences between measurements and
                      model are attributed to a major interference of the GC
                      system to peroxyacyl nitrates. In addition modifications to
                      the rate constants in the MCM are suggested.},
      keywords     = {J (WoSType)},
      cin          = {ICG-II / JARA-ENERGY},
      ddc          = {550},
      cid          = {I:(DE-Juel1)VDB48 / $I:(DE-82)080011_20140620$},
      pnm          = {Atmosphäre und Klima},
      pid          = {G:(DE-Juel1)FUEK406},
      shelfmark    = {Geosciences, Multidisciplinary},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000240943400002},
      doi          = {10.1029/2006GL026778},
      url          = {https://juser.fz-juelich.de/record/52213},
}