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000052269 084__ $$2WoS$$aChemistry, Multidisciplinary
000052269 084__ $$2WoS$$aChemistry, Physical
000052269 084__ $$2WoS$$aMaterials Science, Multidisciplinary
000052269 1001_ $$0P:(DE-Juel1)130719$$aHolmqvist, P.$$b0$$uFZJ
000052269 245__ $$aCrystallization Kinetics of Colloidal Spheres under Stationary Shear Flow
000052269 260__ $$aWashington, DC$$bACS Publ.$$c2005
000052269 300__ $$a10976 - 10982
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000052269 520__ $$aA systematic experimental study of dispersions of charged colloidal spheres is presented on the effect of steady shear flow on nucleation and crystal growth rates. In addition, the nonequilibrium phase diagram as it relates to the melting line is measured. Shear flow is found to strongly affect induction times, crystal growth rates, and the location of the melting line. The main findings are that (1) the crystal growth rate for a given concentration exhibits a maximum as a function of the shear rate; (2) contrary to the monotonic increase in the growth rate with increasing concentration in the absence of flow, a maximum of the crystal growth rate as a function of concentration is observed for sheared systems; and (3) the induction time for a given concentration exhibits a maximum as a function of the shear rate. These findings are partly explained on a qualitative level.
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000052269 7001_ $$0P:(DE-Juel1)130797$$aLettinga, M. P.$$b1$$uFZJ
000052269 7001_ $$0P:(DE-Juel1)130577$$aBuitenhuis, J.$$b2$$uFZJ
000052269 7001_ $$0P:(DE-Juel1)130616$$aDhont, J. K. G.$$b3$$uFZJ
000052269 773__ $$0PERI:(DE-600)2005937-1$$a10.1021/la051490h$$gVol. 21, p. 10976 - 10982$$p10976 - 10982$$q21<10976 - 10982$$tLangmuir$$v21$$x0743-7463$$y2005
000052269 8567_ $$uhttp://hdl.handle.net/2128/1208$$uhttp://dx.doi.org/10.1021/la051490h
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