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@ARTICLE{Mokrousov:52857,
author = {Mokrousov, Y. and Atodiresei, N. and Bihlmayer, G. and
Blügel, S.},
title = {{M}agnetic {A}nisotropy {E}nergies of {M}etal-{B}enzene
{S}andwiches},
journal = {International Journal of Quantum Chemistry},
volume = {106},
issn = {0020-7602},
address = {New York, NY},
publisher = {Wiley},
reportid = {PreJuSER-52857},
pages = {3208 - 3213},
year = {2006},
note = {Record converted from VDB: 12.11.2012},
abstract = {We report on ab initio calculations of the electronic and
magnetic properties of metal-benzene sandwiches M-n(C6H6)(m)
(M = V, Nb, Ta) and infinite wires, obtained by an infinite
repetition of metal-benzene half-sandwiches, based on the
density functional theory (DFT) in the generalized gradient
approximation (GGA). Because of the increasing influence of
the spin-orbit interaction on the magnetic properties, as
going from V to Ta, a significant increase of the magnetic
anisotropy energy (MAE) in the molecules is observed. In
particular, an infinite Nb-benzene wire is predicted to
change its ballistic conductance upon changing of
magnetization direction (ballistic anisotropic
magnetoresistance). The origin of the peculiar magnetic
properties of the molecules is analyzed, and new possible
technological applications are proposed. (c) 2006 Wiley
Periodicals, Inc.},
keywords = {J (WoSType)},
cin = {IFF-TH-I / CNI / JARA-FIT / JARA-SIM},
ddc = {540},
cid = {I:(DE-Juel1)VDB30 / I:(DE-Juel1)VDB381 /
$I:(DE-82)080009_20140620$ / I:(DE-Juel1)VDB1045},
pnm = {Grundlagen für zukünftige Informationstechnologien},
pid = {G:(DE-Juel1)FUEK412},
shelfmark = {Chemistry, Physical / Mathematics, Interdisciplinary
Applications / Physics, Atomic, Molecular $\&$ Chemical},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000241642400022},
doi = {10.1002/qua.21139},
url = {https://juser.fz-juelich.de/record/52857},
}