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@ARTICLE{Rudich:52925,
author = {Rudich, Y. and Donahue, N. and Mentel, T. F.},
title = {{A}ging of organic aerosols: bridging the gap between
laboratory and field studies},
journal = {Annual review of physical chemistry},
volume = {58},
issn = {0066-426X},
address = {Palo Alto, Calif. [u.a.]},
publisher = {Annual Reviews},
reportid = {PreJuSER-52925},
pages = {321 - 352},
year = {2007},
note = {Record converted from VDB: 12.11.2012},
abstract = {The oxidation of organics in aerosol particles affects the
physical properties of aerosols through a process known as
aging. Atmospheric particles compose a huge set of specific
organic compounds, most of which have not been identified in
field measurements. Laboratory experiments inevitably
address model systems of reduced complexity to isolate
critical chemical phenomena, but growing evidence suggests
that composition effects may play a central role in the
atmospheric aging of organic particles. In this review we
seek to address the connections between recent laboratory
studies and recent field campaigns addressing the aging of
organic aerosols. We review laboratory studies on the uptake
of oxidants, the evolution of particle-water interactions,
and the evolution of particle density with aging. Finally,
we review field data addressing condensed-phase lifetimes of
organic tracers. These data suggest that although matrix
effects identified in the laboratory have taken a step
toward reconciling laboratory-field disagreements, further
work is needed to understand the actual aging rates of
organics in ambient particles.},
keywords = {Aerosols: chemistry / Organic Chemicals: chemistry /
Oxidation-Reduction / Ozone: chemistry / Research: methods /
Time Factors / Aerosols (NLM Chemicals) / Organic Chemicals
(NLM Chemicals) / Ozone (NLM Chemicals) / J (WoSType)},
cin = {ICG-2},
ddc = {540},
cid = {I:(DE-Juel1)VDB791},
pnm = {Atmosphäre und Klima},
pid = {G:(DE-Juel1)FUEK406},
shelfmark = {Chemistry, Physical},
typ = {PUB:(DE-HGF)16},
pubmed = {pmid:17090227},
UT = {WOS:000246652300013},
doi = {10.1146/annurev.physchem.58.032806.104432},
url = {https://juser.fz-juelich.de/record/52925},
}