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000053109 0247_ $$2DOI$$a10.1016/j.chemosphere.2006.08.012
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000053109 084__ $$2WoS$$aEnvironmental Sciences
000053109 1001_ $$0P:(DE-HGF)0$$aZhang, H.$$b0
000053109 245__ $$aEnantioselective separation and determination of single nonylphenol isomers
000053109 260__ $$aAmsterdam [u.a.]$$bElsevier Science$$c2007
000053109 300__ $$a594 - 602
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000053109 440_0 $$01228$$aChemosphere$$v66$$x0045-6535
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000053109 520__ $$aIt has recently become clear that an isomer specific view of technical 4-nonylphenol (NP) is absolutely necessary for the evaluation of the biological behavior of NP, raising additional questions concerning enantiomer specific effects. For the first time, in this study enantioselective HPLC was applied to enantiomeric separation of chiral NP isomers. A semipreparative separation of two NP isomers could be achieved. A GC-MS method has been developed for the simultaneous detection of three chiral NP isomers in water samples. Investigation of influent and effluent samples from a wastewater treatment plant in Germany indicated that enantioselective degradation could occur in the environment. In one examined influent, an enantiomer ratio of 1.7 for two different isomers was determined.
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000053109 650_2 $$2MeSH$$aChromatography, High Pressure Liquid
000053109 650_2 $$2MeSH$$aGas Chromatography-Mass Spectrometry: methods
000053109 650_2 $$2MeSH$$aGermany
000053109 650_2 $$2MeSH$$aIsomerism
000053109 650_2 $$2MeSH$$aPhenols: analysis
000053109 650_2 $$2MeSH$$aWater Pollutants, Chemical: analysis
000053109 650_7 $$00$$2NLM Chemicals$$aPhenols
000053109 650_7 $$00$$2NLM Chemicals$$aWater Pollutants, Chemical
000053109 650_7 $$025154-52-3$$2NLM Chemicals$$anonylphenol
000053109 650_7 $$2WoSType$$aJ
000053109 65320 $$2Author$$anonylphenol
000053109 65320 $$2Author$$achiral separation
000053109 65320 $$2Author$$awastewater treatment plant (WWTP)
000053109 7001_ $$0P:(DE-HGF)0$$aZuehlke, S.$$b1
000053109 7001_ $$0P:(DE-Juel1)129325$$aGünther, K.$$b2$$uFZJ
000053109 7001_ $$0P:(DE-HGF)0$$aSpiteller, M.$$b3
000053109 773__ $$0PERI:(DE-600)1496851-4$$a10.1016/j.chemosphere.2006.08.012$$gVol. 66, p. 594 - 602$$p594 - 602$$q66<594 - 602$$tChemosphere$$v66$$x0045-6535$$y2007
000053109 8567_ $$uhttp://dx.doi.org/10.1016/j.chemosphere.2006.08.012
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000053109 915__ $$0StatID:(DE-HGF)0010$$aJCR/ISI refereed
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