001     53121
005     20240708132826.0
024 7 _ |2 DOI
|a 10.1016/j.ssi.2006.08.025
024 7 _ |2 WOS
|a WOS:000242728100003
037 _ _ |a PreJuSER-53121
041 _ _ |a eng
082 _ _ |a 530
084 _ _ |2 WoS
|a Chemistry, Physical
084 _ _ |2 WoS
|a Physics, Condensed Matter
100 1 _ |a Meulenberg, W. A.
|b 0
|u FZJ
|0 P:(DE-Juel1)129637
245 _ _ |a Preparation of proton conducting BaCe0.8Gd0.2O3 thin films
260 _ _ |a Amsterdam [u.a.]
|b Elsevier Science
|c 2006
300 _ _ |a 2851 - 2856
336 7 _ |a Journal Article
|0 PUB:(DE-HGF)16
|2 PUB:(DE-HGF)
336 7 _ |a Output Types/Journal article
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336 7 _ |a Journal Article
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336 7 _ |a ARTICLE
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336 7 _ |a JOURNAL_ARTICLE
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336 7 _ |a article
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440 _ 0 |a Solid State Ionics
|x 0167-2738
|0 5565
|v 177
500 _ _ |a Record converted from VDB: 12.11.2012
520 _ _ |a Thin films of BaCe0.8Gd0.2O3 were prepared by solid state reaction of two screen-printed layers over porous substrates. The first layer consists of the oxygen ion conductor Ce0.8Gd0.2O2 with a fluorite structure, whereas the top layer consists of BaCO3. After decomposition of the carbonate, BaO reacts with Ce0.8Gd0.2O2 forming the perovskite oxide BaCe0.8Gd0.2O3-delta with protonic conductivity. The in-situ reaction and densification on the porous substrates results in gastight thin layers of 10 to 50 pm and allows overcoming the problems due to the poor sinterability of the proton conductor. Two different porous substrates prepared by warm-pressing were studied as membrane supports, i.e., (i) porous composite NiO-Zr0.85Y0.15O2, commonly employed as solid oxide fuel cell anode and (ii) porous Ce0.8Gd0.2O2 oxide. The structural properties of the layer, compositional gradients and occurring phases are described, as well as water uptake, gastightness (He leaking rate) and emf measurement. Protonic conducting membranes are particularly suited not only for hydrogen separation combined with reforming and water-gas-shift converters but also as a protonic fuel cell electrolyte. (c) 2006 Elsevier B.V. All rights reserved.
536 _ _ |a Rationelle Energieumwandlung
|c P12
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588 _ _ |a Dataset connected to Web of Science
650 _ 7 |a J
|2 WoSType
653 2 0 |2 Author
|a proton conductor
653 2 0 |2 Author
|a perovskite
653 2 0 |2 Author
|a membrane
653 2 0 |2 Author
|a hydrogen separation
653 2 0 |2 Author
|a barium cerate
700 1 _ |a Serra, J. M.
|b 1
|u FZJ
|0 P:(DE-Juel1)VDB55636
700 1 _ |a Schober, T.
|b 2
|u FZJ
|0 P:(DE-Juel1)VDB3067
773 _ _ |a 10.1016/j.ssi.2006.08.025
|g Vol. 177, p. 2851 - 2856
|p 2851 - 2856
|q 177<2851 - 2856
|0 PERI:(DE-600)1500750-9
|t Solid state ionics
|v 177
|y 2006
|x 0167-2738
856 7 _ |u http://dx.doi.org/10.1016/j.ssi.2006.08.025
909 C O |o oai:juser.fz-juelich.de:53121
|p VDB
913 1 _ |k P12
|v Rationelle Energieumwandlung
|l Rationelle Energieumwandlung
|b Energie
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914 1 _ |y 2006
915 _ _ |0 StatID:(DE-HGF)0010
|a JCR/ISI refereed
920 1 _ |k IWV-1
|l Werkstoffsynthese und Herstellungsverfahren
|d 31.12.2006
|g IWV
|0 I:(DE-Juel1)VDB5
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980 _ _ |a UNRESTRICTED
981 _ _ |a I:(DE-Juel1)IMD-2-20101013
981 _ _ |a I:(DE-Juel1)IEK-1-20101013


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