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@ARTICLE{Kazempoor:53334,
      author       = {Kazempoor, M. and Pirug, G.},
      title        = {{C}omplex {F}ormation and {P}roton {T}ransfer between
                      {F}ormic {A}cid and {W}ater {A}dsorbed on {A}u(111)
                      {S}urfaces under {UHV} {C}onditions},
      journal      = {Applied physics / A},
      volume       = {87},
      issn         = {0947-8396},
      address      = {Berlin},
      publisher    = {Springer},
      reportid     = {PreJuSER-53334},
      pages        = {435 - 441},
      year         = {2007},
      note         = {Record converted from VDB: 12.11.2012},
      abstract     = {The coadsorption of formic acid and water on Au(111)
                      surfaces has been investigated by means of vibrational and
                      photoelectron spectroscopy (HREELS, XPS). Formic acid
                      adsorbs at 90 K molecularly with vibrational modes
                      characteristic for flat lying zig-zag chains in the mono-
                      and multilayer regime, like in solid formic acid. Annealing
                      results in a complete desorption at 190 K. Sequential
                      adsorption of formic acid and water at 90 K shows no
                      significant chemical interaction. Upon annealing the
                      coadsorbed layer to 140 K a hydrogen-bonded cyclic complex
                      of formic acid with one water molecule could be identified
                      using isotopically labelled adsorbates (D2O, (HCOOD)-C-13).
                      Upon further annealing this complex decomposes leaving
                      molecularly adsorbed formic acid on the surface at 160 K,
                      accompanied by a proton exchange between formic acid and
                      water.},
      keywords     = {J (WoSType)},
      cin          = {IBN-3 / CNI / JARA-FIT},
      ddc          = {530},
      cid          = {I:(DE-Juel1)VDB801 / I:(DE-Juel1)VDB381 /
                      $I:(DE-82)080009_20140620$},
      pnm          = {Grundlagen für zukünftige Informationstechnologien},
      pid          = {G:(DE-Juel1)FUEK412},
      shelfmark    = {Materials Science, Multidisciplinary / Physics, Applied},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000244950900015},
      doi          = {10.1007/s00339-007-3926-8},
      url          = {https://juser.fz-juelich.de/record/53334},
}