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@ARTICLE{Tripathi:53477,
author = {Tripathi, O. P. and Godin-Beekmann, S. and Pazmino, A. and
Lefevree, F. and Marchand, M. and Hauchecorne, A. and
Goutail, F. and Schlager, H. and Volk, C. M. and Johnson, B.
and König-Langlo, G. and Balestri, S. and Stroh, F. and
Bui, T. P. and Jost, H. J. and Deshler, T. and von der
Gathen, P.},
title = {{H}igh resolution simulation of recent {A}rctic and
{A}ntarctic stratospheric chemical ozone loss compared to
observations},
journal = {Journal of atmospheric chemistry},
volume = {55},
issn = {0167-7764},
address = {Dordrecht [u.a.]},
publisher = {Springer Science + Business Media B.V},
reportid = {PreJuSER-53477},
pages = {205 - 226},
year = {2006},
note = {Record converted from VDB: 12.11.2012},
abstract = {Simulations of polar ozone losses were performed using the
three-dimensional high-resolution (1 degrees x 1 degrees)
chemical transport model MIMOSA-CHIM. Three Arctic winters
1999-2000, 2001-2002, 2002-2003 and three Antarctic winters
2001, 2002, and 2003 were considered for the study. The
cumulative ozone loss in the Arctic winter 2002-2003 reached
around $35\%$ at 475 K inside the vortex, as compared to
more than $60\%$ in 1999-2000. During 1999-2000,
denitrification induces a maximum of about $23\%$ extra
ozone loss at 475 K as compared to $17\%$ in 2002-2003.
Unlike these two colder Arctic winters, the 2001-2002 Arctic
was warmer and did not experience much ozone loss.
Sensitivity tests showed that the chosen resolution of 1
degrees x 1 degrees provides a better evaluation of ozone
loss at the edge of the polar vortex in high solar zenith
angle conditions. The simulation results for ozone, ClO,
HNO3, N2O, and NOy for winters 1999-2000 and 2002-2003 were
compared with measurements on board ER-2 and Geophysica
aircraft respectively. Sensitivity tests showed that
increasing heating rates calculated by the model by $50\%$
and doubling the PSC (Polar Stratospheric Clouds) particle
density (from 5 x 10(-3) to 10(-2) cm(-3)) refines the
agreement with in situ ozone, N2O and NOy levels. In this
configuration, simulated ClO levels are increased and are in
better agreement with observations in January but are
overestimated by about $20\%$ in March. The use of the
Burkholder et al. (1990) Cl2O2 absorption cross-sections
slightly increases further ClO levels especially in high
solar zenith angle conditions. Comparisons of the modelled
ozone values with ozonesonde measurement in the Antarctic
winter 2003 and with Polar Ozone and Aerosol Measurement III
(POAM III) measurements in the Antarctic winters 2001 and
2002, shows that the simulations underestimate the ozone
loss rate at the end of the ozone destruction period. A
slightly better agreement is obtained with the use of
Burkholder et al. (1990) Cl2O2 absorption cross-sections.},
keywords = {J (WoSType)},
cin = {ICG-I},
ddc = {540},
cid = {I:(DE-Juel1)VDB47},
pnm = {Atmosphäre und Klima},
pid = {G:(DE-Juel1)FUEK406},
shelfmark = {Environmental Sciences / Meteorology $\&$ Atmospheric
Sciences},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000241797000002},
doi = {10.1007/s10874-006-9028-8},
url = {https://juser.fz-juelich.de/record/53477},
}