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000053548 084__ $$2WoS$$aChemistry, Physical
000053548 1001_ $$0P:(DE-HGF)0$$aMeier, R. J.$$b0
000053548 245__ $$aDetecting the effect of very low amounts of penetrants in lipid bilayers using Raman spectroscopy
000053548 260__ $$aWashington, DC$$bSoc.$$c2006
000053548 300__ $$a20727 - 20728
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000053548 440_0 $$03694$$aJournal of Physical Chemistry B$$v110$$x1520-6106
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000053548 520__ $$aWe show that, by the influence on the gauche content in the acyl chains, the effect of very low concentrations (order 10(-2) %) of penetrants (here 2,4-dichlorophenol) in lipid bilayers (here dipalmitoyl-glycerophosphatidylcholine) can be experimentally seen in the Raman spectra. The observed effects suggest increased order and are in accordance with previous X-ray diffraction and calorimetric data. These findings show great promise for studying in situ the effect of low amounts of various small molecules on cell membranes using Raman spectroscopy.
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000053548 650_2 $$2MeSH$$a1,2-Dipalmitoylphosphatidylcholine
000053548 650_2 $$2MeSH$$aLipid Bilayers: metabolism
000053548 650_2 $$2MeSH$$aOrganic Chemicals: pharmacokinetics
000053548 650_2 $$2MeSH$$aPermeability: drug effects
000053548 650_2 $$2MeSH$$aPhase Transition: drug effects
000053548 650_2 $$2MeSH$$aSpectrum Analysis, Raman
000053548 650_7 $$00$$2NLM Chemicals$$aLipid Bilayers
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000053548 650_7 $$02644-64-6$$2NLM Chemicals$$a1,2-Dipalmitoylphosphatidylcholine
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000053548 7001_ $$0P:(DE-Juel1)128805$$aCsiszár, A.$$b1$$uFZJ
000053548 7001_ $$0P:(DE-Juel1)129484$$aKlumpp, E.$$b2$$uFZJ
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000053548 8567_ $$uhttp://hdl.handle.net/2128/799$$uhttp://dx.doi.org/10.1021/jp0615757
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