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@ARTICLE{Persson:53860,
author = {Persson, B. N. J. and Zhao, K. and Zhang, Z. Y.},
title = {{C}hemical contribution to surface-enhanced {R}aman
scattering},
journal = {Physical review letters},
volume = {96},
issn = {0031-9007},
address = {College Park, Md.},
publisher = {APS},
reportid = {PreJuSER-53860},
pages = {207401},
year = {2006},
note = {Record converted from VDB: 12.11.2012},
abstract = {We present a new mechanism for the chemical contribution to
surface-enhanced Raman scattering (SERS). The theory
considers the modulation of the polarizability of a metal
nanocluster or a flat metal surface by the vibrational
motion of an adsorbed molecule. The modulated polarization
of the substrate coupled with the incident light will
contribute to the Raman scattering enhancement. We show that
for a metal cluster and for a flat metal surface this new
chemical contribution may enhance the Raman scattering
intensity by a factor of similar to 10(2) and similar to
10(4), respectively. The new SERS process is determined by
the electric field parallel to the surface of the metal
substrate at the molecular binding site.},
keywords = {J (WoSType)},
cin = {IFF-TH-I},
ddc = {550},
cid = {I:(DE-Juel1)VDB30},
pnm = {Kondensierte Materie},
pid = {G:(DE-Juel1)FUEK414},
shelfmark = {Physics, Multidisciplinary},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000237847000050},
doi = {10.1103/PhysRevLett.96.207401},
url = {https://juser.fz-juelich.de/record/53860},
}