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000054384 084__ $$2WoS$$aPhysics, Condensed Matter
000054384 1001_ $$0P:(DE-Juel1)VDB4228$$aFrielinghaus, H.$$b0$$uFZJ
000054384 245__ $$aSANS studies of confined diblock copolymers in microemulsions
000054384 260__ $$aAmsterdam$$bNorth-Holland Physics Publ.$$c2006
000054384 300__ $$a738 - 741
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000054384 440_0 $$04907$$aPhysica B: Condensed Matter$$v385-386$$x0921-4526
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000054384 520__ $$aUsing small angle neutron scattering (SANS) polymers were studied as additives in microemulsions. Usually, one assumes no or small confinement, which is expressed by the ratio of the polymer size R-g and the domain size d. For amphiphilic diblock copolymers, an increased surfactant efficiency and a more rigid surfactant membrane were observed. The sensitivity of the diblock copolymer effect on polymer concentration agreed with theoretical predictions. The current study is focused on medium and higher confinement of diblock copolymers. A computer simulation predicted elevated sensitivities for medium confinement and a reversed behaviour for high confinement. Experimentally, we found evidence for the reversal between medium and high confinement. The correlation length, which is proportional to the membrane rigidity, increased or decreased depending on the level of confinement. This result supports the interpretation that at high confinement the anchored diblock copolymer and the free homopolymer cannot be distinguished anymore. (c) 2006 Elsevier B.V. All rights reserved.
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000054384 65320 $$2Author$$asmall angle neutron scattering
000054384 65320 $$2Author$$amicroemulsion
000054384 65320 $$2Author$$apolymer
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000054384 7001_ $$0P:(DE-Juel1)VDB56501$$aMaccarrone, S.$$b1$$uFZJ
000054384 7001_ $$0P:(DE-Juel1)VDB4227$$aByelov, D.$$b2$$uFZJ
000054384 7001_ $$0P:(DE-Juel1)130501$$aAllgaier, J.$$b3$$uFZJ
000054384 7001_ $$0P:(DE-Juel1)130917$$aRichter, D.$$b4$$uFZJ
000054384 7001_ $$0P:(DE-Juel1)130514$$aAuth, T.$$b5$$uFZJ
000054384 7001_ $$0P:(DE-Juel1)130665$$aGompper, G.$$b6$$uFZJ
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000054384 8567_ $$uhttp://dx.doi.org/10.1016/j.physb.2006.06.076
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