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@ARTICLE{Frielinghaus:54384,
author = {Frielinghaus, H. and Maccarrone, S. and Byelov, D. and
Allgaier, J. and Richter, D. and Auth, T. and Gompper, G.},
title = {{SANS} studies of confined diblock copolymers in
microemulsions},
journal = {Physica / B},
volume = {385-386},
issn = {0921-4526},
address = {Amsterdam},
publisher = {North-Holland Physics Publ.},
reportid = {PreJuSER-54384},
pages = {738 - 741},
year = {2006},
note = {Record converted from VDB: 12.11.2012},
abstract = {Using small angle neutron scattering (SANS) polymers were
studied as additives in microemulsions. Usually, one assumes
no or small confinement, which is expressed by the ratio of
the polymer size R-g and the domain size d. For amphiphilic
diblock copolymers, an increased surfactant efficiency and a
more rigid surfactant membrane were observed. The
sensitivity of the diblock copolymer effect on polymer
concentration agreed with theoretical predictions. The
current study is focused on medium and higher confinement of
diblock copolymers. A computer simulation predicted elevated
sensitivities for medium confinement and a reversed
behaviour for high confinement. Experimentally, we found
evidence for the reversal between medium and high
confinement. The correlation length, which is proportional
to the membrane rigidity, increased or decreased depending
on the level of confinement. This result supports the
interpretation that at high confinement the anchored diblock
copolymer and the free homopolymer cannot be distinguished
anymore. (c) 2006 Elsevier B.V. All rights reserved.},
keywords = {J (WoSType)},
cin = {IFF-INS / IFF-ISM / Jülich Centre for Neutron Science JCNS
(JCNS) ; JCNS / IFF-TH-II / JARA-SIM},
ddc = {530},
cid = {I:(DE-Juel1)VDB341 / I:(DE-Juel1)VDB342 /
I:(DE-Juel1)JCNS-20121112 / I:(DE-Juel1)VDB31 /
I:(DE-Juel1)VDB1045},
pnm = {Kondensierte Materie / Großgeräte für die Forschung mit
Photonen, Neutronen und Ionen (PNI)},
pid = {G:(DE-Juel1)FUEK414 / G:(DE-Juel1)FUEK415},
shelfmark = {Physics, Condensed Matter},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000243096400219},
doi = {10.1016/j.physb.2006.06.076},
url = {https://juser.fz-juelich.de/record/54384},
}