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@ARTICLE{Serra:55694,
author = {Serra, J. M. and Büchler, O. and Meulenberg, W. A. and
Buchkremer, H. P.},
title = {{T}hin {B}a{C}e0.8{G}d0.2{O}3-delta {P}rotonic
{E}lectrolytes on porous {C}e08{G}d0.2{O}1.9-{N}i
{S}ubstrates},
journal = {Journal of the Electrochemical Society},
volume = {154},
issn = {0013-4651},
address = {Pennington, NJ},
publisher = {Electrochemical Society},
reportid = {PreJuSER-55694},
pages = {B334 - B340},
year = {2007},
note = {Record converted from VDB: 12.11.2012},
abstract = {Thin proton-conducting electrolytes with 20 mu m thickness
and a nominal composition BaCe0.8Gd0.2O3-delta were prepared
over porous substrates composed of Ce0.8Gd0.2O1.9 (CGO)-Ni.
The fabrication method includes the simultaneous cofiring
and solid-state reaction at 1300 degrees C of three
screen-printed layers: mixed conducting anode layer, CGO,
and an upper-coated BaCO3 layer. The resulting asymmetric
membranes with 5 X 5 cm(2) geometry are gastight. The
solid-state reaction resulted in the formation of (i) an
electrolyte with large (similar to 2-5 mu m) grains and high
packing density and (ii) anode layer comprising finely
grained BaCe0.8Gd0.2O3-delta and Ni particles with a
thickness around 5 mu m. The layer morphology, phase
distribution, and lattice composition has been investigated
by X-ray diffraction, energy-dispersive spectroscopy
scanning electron microscopy, and secondary-ion mass
spectrometry. The preparation of the substrate by
warm-pressing and tailoring of the porosity and sintering
activity are also thoroughly described. DC-electrical
conductivity and ac-electrochemical characterization showed
that the supported Gd-doped barium cerate electrolyte
produced by solid-state reaction has interesting
proton-conduction properties for application in solid oxide
fuel cells, hydrogen separation, and sensors. (c) 2007 The
Electrochemical Society.},
keywords = {J (WoSType)},
cin = {IEF-1},
ddc = {540},
cid = {I:(DE-Juel1)VDB809},
pnm = {Rationelle Energieumwandlung / SOFC - Solid Oxide Fuel Cell
(SOFC-20140602)},
pid = {G:(DE-Juel1)FUEK402 / G:(DE-Juel1)SOFC-20140602},
shelfmark = {Electrochemistry / Materials Science, Coatings $\&$ Films},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000243977500023},
doi = {10.1149/1.2422901},
url = {https://juser.fz-juelich.de/record/55694},
}