Home > Publications database > Thin BaCe0.8Gd0.2O3-delta Protonic Electrolytes on porous Ce08Gd0.2O1.9-Ni Substrates > print |
001 | 55694 | ||
005 | 20240708132836.0 | ||
024 | 7 | _ | |a 10.1149/1.2422901 |2 DOI |
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024 | 7 | _ | |a 0013-4651 |2 ISSN |
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041 | _ | _ | |a eng |
082 | _ | _ | |a 540 |
084 | _ | _ | |2 WoS |a Electrochemistry |
084 | _ | _ | |2 WoS |a Materials Science, Coatings & Films |
100 | 1 | _ | |a Serra, J. M. |b 0 |u FZJ |0 P:(DE-Juel1)VDB55636 |
245 | _ | _ | |a Thin BaCe0.8Gd0.2O3-delta Protonic Electrolytes on porous Ce08Gd0.2O1.9-Ni Substrates |
260 | _ | _ | |a Pennington, NJ |b Electrochemical Society |c 2007 |
300 | _ | _ | |a B334 - B340 |
336 | 7 | _ | |a Journal Article |0 PUB:(DE-HGF)16 |2 PUB:(DE-HGF) |
336 | 7 | _ | |a Output Types/Journal article |2 DataCite |
336 | 7 | _ | |a Journal Article |0 0 |2 EndNote |
336 | 7 | _ | |a ARTICLE |2 BibTeX |
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336 | 7 | _ | |a article |2 DRIVER |
440 | _ | 0 | |a Journal of the Electrochemical Society |x 0013-4651 |0 3889 |y 3 |v 154 |
500 | _ | _ | |a Record converted from VDB: 12.11.2012 |
520 | _ | _ | |a Thin proton-conducting electrolytes with 20 mu m thickness and a nominal composition BaCe0.8Gd0.2O3-delta were prepared over porous substrates composed of Ce0.8Gd0.2O1.9 (CGO)-Ni. The fabrication method includes the simultaneous cofiring and solid-state reaction at 1300 degrees C of three screen-printed layers: mixed conducting anode layer, CGO, and an upper-coated BaCO3 layer. The resulting asymmetric membranes with 5 X 5 cm(2) geometry are gastight. The solid-state reaction resulted in the formation of (i) an electrolyte with large (similar to 2-5 mu m) grains and high packing density and (ii) anode layer comprising finely grained BaCe0.8Gd0.2O3-delta and Ni particles with a thickness around 5 mu m. The layer morphology, phase distribution, and lattice composition has been investigated by X-ray diffraction, energy-dispersive spectroscopy scanning electron microscopy, and secondary-ion mass spectrometry. The preparation of the substrate by warm-pressing and tailoring of the porosity and sintering activity are also thoroughly described. DC-electrical conductivity and ac-electrochemical characterization showed that the supported Gd-doped barium cerate electrolyte produced by solid-state reaction has interesting proton-conduction properties for application in solid oxide fuel cells, hydrogen separation, and sensors. (c) 2007 The Electrochemical Society. |
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700 | 1 | _ | |a Meulenberg, W. A. |b 2 |u FZJ |0 P:(DE-Juel1)129637 |
700 | 1 | _ | |a Buchkremer, H. P. |b 3 |u FZJ |0 P:(DE-Juel1)129594 |
773 | _ | _ | |a 10.1149/1.2422901 |g Vol. 154, p. B334 - B340 |p B334 - B340 |q 154 |t Journal of the Electrochemical Society |v 154 |y 2007 |x 0013-4651 |
856 | 7 | _ | |u http://dx.doi.org/10.1149/1.2422901 |
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