001     55694
005     20240708132836.0
024 7 _ |a 10.1149/1.2422901
|2 DOI
024 7 _ |a WOS:000243977500023
|2 WOS
024 7 _ |a 0013-4651
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024 7 _ |a 0096-4743
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024 7 _ |a 0096-4786
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024 7 _ |a 1945-7111
|2 ISSN
037 _ _ |a PreJuSER-55694
041 _ _ |a eng
082 _ _ |a 540
084 _ _ |2 WoS
|a Electrochemistry
084 _ _ |2 WoS
|a Materials Science, Coatings & Films
100 1 _ |a Serra, J. M.
|b 0
|u FZJ
|0 P:(DE-Juel1)VDB55636
245 _ _ |a Thin BaCe0.8Gd0.2O3-delta Protonic Electrolytes on porous Ce08Gd0.2O1.9-Ni Substrates
260 _ _ |a Pennington, NJ
|b Electrochemical Society
|c 2007
300 _ _ |a B334 - B340
336 7 _ |a Journal Article
|0 PUB:(DE-HGF)16
|2 PUB:(DE-HGF)
336 7 _ |a Output Types/Journal article
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336 7 _ |a Journal Article
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336 7 _ |a ARTICLE
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336 7 _ |a JOURNAL_ARTICLE
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336 7 _ |a article
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440 _ 0 |a Journal of the Electrochemical Society
|x 0013-4651
|0 3889
|y 3
|v 154
500 _ _ |a Record converted from VDB: 12.11.2012
520 _ _ |a Thin proton-conducting electrolytes with 20 mu m thickness and a nominal composition BaCe0.8Gd0.2O3-delta were prepared over porous substrates composed of Ce0.8Gd0.2O1.9 (CGO)-Ni. The fabrication method includes the simultaneous cofiring and solid-state reaction at 1300 degrees C of three screen-printed layers: mixed conducting anode layer, CGO, and an upper-coated BaCO3 layer. The resulting asymmetric membranes with 5 X 5 cm(2) geometry are gastight. The solid-state reaction resulted in the formation of (i) an electrolyte with large (similar to 2-5 mu m) grains and high packing density and (ii) anode layer comprising finely grained BaCe0.8Gd0.2O3-delta and Ni particles with a thickness around 5 mu m. The layer morphology, phase distribution, and lattice composition has been investigated by X-ray diffraction, energy-dispersive spectroscopy scanning electron microscopy, and secondary-ion mass spectrometry. The preparation of the substrate by warm-pressing and tailoring of the porosity and sintering activity are also thoroughly described. DC-electrical conductivity and ac-electrochemical characterization showed that the supported Gd-doped barium cerate electrolyte produced by solid-state reaction has interesting proton-conduction properties for application in solid oxide fuel cells, hydrogen separation, and sensors. (c) 2007 The Electrochemical Society.
536 _ _ |a Rationelle Energieumwandlung
|c P12
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536 _ _ |a SOFC - Solid Oxide Fuel Cell (SOFC-20140602)
|0 G:(DE-Juel1)SOFC-20140602
|c SOFC-20140602
|x 1
|f SOFC
588 _ _ |a Dataset connected to Web of Science, Pubmed
650 _ 7 |a J
|2 WoSType
700 1 _ |a Büchler, O.
|b 1
|u FZJ
|0 P:(DE-Juel1)VDB50856
700 1 _ |a Meulenberg, W. A.
|b 2
|u FZJ
|0 P:(DE-Juel1)129637
700 1 _ |a Buchkremer, H. P.
|b 3
|u FZJ
|0 P:(DE-Juel1)129594
773 _ _ |a 10.1149/1.2422901
|g Vol. 154, p. B334 - B340
|p B334 - B340
|q 154|0 PERI:(DE-600)2002179-3
|t Journal of the Electrochemical Society
|v 154
|y 2007
|x 0013-4651
856 7 _ |u http://dx.doi.org/10.1149/1.2422901
909 C O |o oai:juser.fz-juelich.de:55694
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913 1 _ |k P12
|v Rationelle Energieumwandlung
|l Rationelle Energieumwandlung
|b Energie
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914 1 _ |y 2007
915 _ _ |0 StatID:(DE-HGF)0010
|a JCR/ISI refereed
920 1 _ |k IEF-1
|l Werkstoffsynthese und Herstellungsverfahren
|d 30.09.2010
|g IEF
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980 _ _ |a UNRESTRICTED
981 _ _ |a I:(DE-Juel1)IMD-2-20101013
981 _ _ |a I:(DE-Juel1)IEK-1-20101013


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