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@ARTICLE{Willsch:56428,
author = {Willsch, H. and Clegg, H. and Horsfield, B. and Radke, M.
and Wilkes, H.},
title = {{L}iquid chromatographic separation of sediment, rock and
coal extracts and crude oil into compound classes},
journal = {Analytical chemistry},
volume = {69},
issn = {0003-2700},
address = {Columbus, Ohio},
publisher = {American Chemical Society},
reportid = {PreJuSER-56428},
pages = {4203 - 4209},
year = {1997},
note = {Record converted from VDB: 12.11.2012},
abstract = {A method is described for the rapid fractionation of
sediment, rock, and coal extracts and crude oils into
compound classes. The method is based on combined
polarity/affinity chromatography of soluble organic matter.
Five heterocompound fractions are obtained in addition to
the conventional saturated and aromatic hydrocarbon
fractions, Model compound studies show that those fractions
are chemically well-defined. The applicability to a variety
of geological materials is demonstrated by analyzing a North
Sea crude oil and solvent extracts of Posidonia shale, coal,
and recent lake sediment samples, Generality
reproducibilities and linearities are satisfactory, The
total recoveries vary between $76\%$ and $57\%,$ depending
on the sample type, The method is shown to be well-suited
for the bulk compositional characterization of soluble
organic matter. Separations can be performed on both the
analytical and the semipreparative scales, Isolated
fractions are amenable directly or after derivatization to
qualitative and quantitative analysis by gas chromatography
and gas chromatography/mass spectrometry.},
keywords = {J (WoSType)},
cin = {ICG-4},
ddc = {540},
cid = {I:(DE-Juel1)VDB793},
pnm = {Kohlenwasserstoffgenese und -migration},
pid = {G:(DE-Juel1)FUEK421},
shelfmark = {Chemistry, Analytical},
typ = {PUB:(DE-HGF)16},
UT = {WOS:A1997YA44600017},
doi = {10.1021/ac9703818},
url = {https://juser.fz-juelich.de/record/56428},
}