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@ARTICLE{Thomas:56487,
author = {Thomas, R. and Ehrhart, P. and Roeckerath, M. and van
Elshocht, S. and Rije, E. and Luysberg, M. and Boese, M. and
Schubert, J. and Caymax, M. and Waser, R.},
title = {{L}iquid {I}njection {MOCVD} of {D}ysprosium {S}candate
{F}ilms: {D}eposition {C}haracteristics and {H}igh-k
{A}pplications},
journal = {Journal of the Electrochemical Society},
volume = {154},
issn = {0013-4651},
address = {Pennington, NJ},
publisher = {Electrochemical Society},
reportid = {PreJuSER-56487},
pages = {G147 - G154},
year = {2007},
note = {Record converted from VDB: 12.11.2012},
abstract = {Crystalline Dy2O3, Sc2O3, and amorphous high-k DyScO3 thin
films have been deposited on Si(100) substrates by
metallorganic chemical vapor deposition (MOCVD) using two
metal precursors M(EDMDD)(3) [M=Dy, Sc; EDMDD=6-Ethyl-2,2-Di
Methyl -3,5-Decane Dionato]. The precursors were evaluated
in terms of efficiency and growth rate under various
conditions, viz. vaporizer and susceptor temperatures,
reactor pressure, injection rate, and injection delay
between the two precursors. Amorphous DyScO3 films with
nearly correct stoichiometry were deposited within the
temperature range of 560-700 degrees C. These amorphous
films were smoother than the crystalline binary oxides and
reached a density of around $85\%$ of the bulk crystalline
density. Amorphous structure and surface smoothness retained
up to an annealing temperature as high as 950 degrees C. The
thickness of the SiOx interlayer did not vary with
deposition temperature, but annealing at temperatures above
900 degrees C increased the interlayer thickness. Electrical
properties are promising; the dielectric constant of DyScO3
(k approximate to 22) is much higher than that of the binary
oxides Dy2O3 and Sc2O3 (k approximate to 10), and the
leakage currents are very low compared to SiO2. (C) 2007 The
Electrochemical Society.},
keywords = {J (WoSType)},
cin = {IBN-1 / CNI / IFF-6 / IFF-8 / JARA-FIT},
ddc = {540},
cid = {I:(DE-Juel1)VDB799 / I:(DE-Juel1)VDB381 /
I:(DE-Juel1)VDB786 / I:(DE-Juel1)VDB788 /
$I:(DE-82)080009_20140620$},
pnm = {Grundlagen für zukünftige Informationstechnologien},
pid = {G:(DE-Juel1)FUEK412},
shelfmark = {Electrochemistry / Materials Science, Coatings $\&$ Films},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000246892000047},
doi = {10.1149/1.2731299},
url = {https://juser.fz-juelich.de/record/56487},
}