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@ARTICLE{HaberPohlmeier:56497,
author = {Haber-Pohlmeier, S. and Abarca Heidemann, K. and Körschen,
H. G. and Kaur Dhiman, H. and Heberle, J. and Schwalbe, H.
and Klein-Seetharaman, J. and Kaupp, U. B. and Pohlmeier,
A.},
title = {{B}inding of {C}a2+ to glutamic acid-rich polypeptides from
the rod outer segment},
journal = {Biophysical journal},
volume = {92},
issn = {0006-3495},
address = {New York, NY},
publisher = {Rockefeller Univ. Press},
reportid = {PreJuSER-56497},
pages = {3207 - 3214},
year = {2007},
note = {Record converted from VDB: 12.11.2012},
abstract = {Rod photoreceptors contain three different glutamic
acid-rich proteins (GARPs) that have been proposed to
control the propagation of Ca(2+) from the site of its entry
at the cyclic nucleotide-gated channel to the cytosol of the
outer segment. We tested this hypothesis by measuring the
binding of Ca(2+) to the following five constructs related
to GARPs of rod photoreceptors: a 32-mer peptide containing
22 carboxylate groups, polyglutamic acid, a recombinant
segment comprising 73 carboxylate groups (GLU), GARP1, and
GARP2. Ca(2+) binding was investigated by means of a
Ca(2+)-sensitive electrode. In all cases, Ca(2+) binds with
low affinity; the half-maximum binding constant K(1/2)
ranges from 6 to 16 mM. The binding stoichiometry between
Ca(2+) ions and carboxylic groups is approximately 1:1; an
exception is GARP2, where a binding stoichiometry of
approximately 1:2 was found. Hydrodynamic radii of 1.6, 2.8,
3.3, 5.7, and 6.7 nm were determined by dynamic light
scattering for the 32-mer, polyglutamic acid, GLU, GARP2,
and GARP1 constructs, respectively. These results suggest
that the peptides as well as GARP1 and GARP2 do not adopt
compact globular structures. We conclude that the structures
should be regarded as loose coils with low-affinity,
high-capacity Ca(2+) binding.},
keywords = {Binding Sites / Calcium: chemistry / Glutamic Acid:
chemistry / Nerve Tissue Proteins: chemistry / Peptides:
chemistry / Protein Binding / Retinal Rod Photoreceptor
Cells: chemistry / Nerve Tissue Proteins (NLM Chemicals) /
Peptides (NLM Chemicals) / Glutamic Acid (NLM Chemicals) /
Calcium (NLM Chemicals) / J (WoSType)},
cin = {ICG-4 / INB-1 / INB-2},
ddc = {570},
cid = {I:(DE-Juel1)VDB793 / I:(DE-Juel1)VDB804 /
I:(DE-Juel1)VDB805},
pnm = {Funktion und Dysfunktion des Nervensystems},
pid = {G:(DE-Juel1)FUEK409},
shelfmark = {Biophysics},
typ = {PUB:(DE-HGF)16},
pubmed = {pmid:17218469},
pmc = {pmc:PMC1852358},
UT = {WOS:000245544100028},
doi = {10.1529/biophysj.106.094847},
url = {https://juser.fz-juelich.de/record/56497},
}