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@ARTICLE{Zhang:56608,
author = {Zhang, Z. and Berns, A. E. and Willbold, S. and Buitenhuis,
J.},
title = {{S}ynthesis of poly(ethylene glycol) ({PEG})-grafted
colloidal silica particles with improved stability in
aqueous solvents},
journal = {Journal of colloid and interface science},
volume = {310},
issn = {0021-9797},
address = {Amsterdam [u.a.]},
publisher = {Elsevier},
reportid = {PreJuSER-56608},
pages = {446 - 455},
year = {2007},
note = {Record converted from VDB: 12.11.2012},
abstract = {The known grafting procedures of colloidal silica particles
with poly(ethylene glycol) (PEG) lead to grafting layers
that detach from the silica surface and dissolve in water
within a few days. We present a new grafting procedure of
PEG onto silica with a significant improvement of the
stability of the grafting layers in aqueous solvents.
Moreover, the procedure avoids any dry states or other
circumstances leading to strong aggregation of the
particles. To achieve the improved water stability, Stöber
silica particles are first pre-coated with a silane coupling
agent (3-aminopropyl)triethoxysilane (APS) to incorporate
active amine groups. The water solubility of the pre-coating
layer was minimized using a combination of APS with
bis-(trimethoxysilylpropyl)amine (BTMOSPA) or
bis-(triethoxysilyl)ethane (BTEOSE). These pre-coated
particles were then reacted with N-succinimidyl ester of
mono-methoxy poly(ethylene glycol) carboxylic acid to form
PEG-grafted silica particles. The particles form stable
dispersions in aqueous solutions as well as several organic
solvents.},
keywords = {J (WoSType)},
cin = {ICG-4 / IFF-7 / ZCH},
ddc = {540},
cid = {I:(DE-Juel1)VDB793 / I:(DE-Juel1)VDB787 /
I:(DE-Juel1)ZCH-20090406},
pnm = {Kondensierte Materie},
pid = {G:(DE-Juel1)FUEK414},
shelfmark = {Chemistry, Physical},
typ = {PUB:(DE-HGF)16},
pubmed = {pmid:17346738},
UT = {WOS:000246459700014},
doi = {10.1016/j.jcis.2007.02.024},
url = {https://juser.fz-juelich.de/record/56608},
}