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@ARTICLE{Papagiannopoulos:56804,
      author       = {Papagiannopoulos, A. and Waigh, T. A. and Hardingham, T.
                      and Heinrich, M.},
      title        = {{S}olution {S}tructure and {D}ynamics of {C}artilage
                      {A}ggrecan},
      journal      = {Biomacromolecules},
      volume       = {7},
      issn         = {1525-7797},
      address      = {Columbus, Ohio},
      publisher    = {American Chemical Soc.},
      reportid     = {PreJuSER-56804},
      pages        = {2162 - 2172},
      year         = {2006},
      note         = {Record converted from VDB: 12.11.2012},
      abstract     = {A versatile atom transfer radical polymerization (ATRP)
                      method for polysaccharide grafting in homogeneous mild
                      conditions without using protecting group chemistry is
                      presented. Water/DMF mixtures with different compositions
                      were used as the solvent. The "grafting-from" approach was
                      used in order to prepare suitable pullulan and dextran ATRP
                      macroinitiators with a well controlled degree of
                      functionalization. Methacrylate and acrylamide monomers were
                      grafted obtaining good control over the number, molecular
                      weight and polydispersity of the grafted chains without
                      homopolymer formation and polysaccharide degradation. The
                      versatility of this method allowed us to prepare comblike
                      derivatives with a wide range of properties (amphiphilic,
                      ionic, and thermoresponsive) by simply changing the solvent
                      composition and the catalyst. This could make possible the
                      synthesis of new interesting biomaterials starting from a
                      wide range of polysaccharides.},
      keywords     = {Carbohydrate Conformation / Free Radicals: chemistry /
                      Hydrolysis / Kinetics / Magnetic Resonance Spectroscopy /
                      Models, Chemical / Polysaccharides: chemical synthesis /
                      Polysaccharides: chemistry / Spectroscopy, Fourier Transform
                      Infrared / Temperature / Free Radicals (NLM Chemicals) /
                      Polysaccharides (NLM Chemicals) / J (WoSType)},
      cin          = {IFF-NST},
      ddc          = {540},
      cid          = {I:(DE-Juel1)VDB34},
      pnm          = {Kondensierte Materie / Großgeräte für die Forschung mit
                      Photonen, Neutronen und Ionen (PNI)},
      pid          = {G:(DE-Juel1)FUEK414 / G:(DE-Juel1)FUEK415},
      shelfmark    = {Biochemistry $\&$ Molecular Biology / Chemistry, Organic /
                      Polymer Science},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:16827582},
      UT           = {WOS:000238848800012},
      doi          = {10.1021/bm0601373},
      url          = {https://juser.fz-juelich.de/record/56804},
}