001     56973
005     20240708132825.0
024 7 _ |2 DOI
|a 10.1111/j.1551-2916.2007.01677.x
024 7 _ |2 WOS
|a WOS:000247756500018
024 7 _ |2 altmetric
|a altmetric:21817061
037 _ _ |a PreJuSER-56973
041 _ _ |a ENG
082 _ _ |a 660
084 _ _ |2 WoS
|a Materials Science, Ceramics
100 1 _ |0 P:(DE-Juel1)VDB55636
|a Serra, J. M.
|b 0
|u FZJ
245 _ _ |a Thin-Film Proton BaZr0.85Y0.15O3 Conducting Electrolytes: Toward an Intermediate-Temperature Solid Oxide Fuel Cell Alternative
260 _ _ |a Oxford [u.a.]
|b Wiley-Blackwell
|c 2007
300 _ _ |a 2082 - 2089
336 7 _ |0 PUB:(DE-HGF)16
|2 PUB:(DE-HGF)
|a Journal Article
336 7 _ |2 DataCite
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336 7 _ |0 0
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|a Journal Article
336 7 _ |2 BibTeX
|a ARTICLE
336 7 _ |2 ORCID
|a JOURNAL_ARTICLE
336 7 _ |2 DRIVER
|a article
440 _ 0 |0 3845
|a Journal of the American Ceramic Society
|v 90
|x 0002-7820
|y 7
500 _ _ |a Record converted from VDB: 12.11.2012
520 _ _ |a A novel method for the preparation of a thin oxidic proton-conducting electrolyte is presented. This kind of supported film was studied in detail as it is applicable for IT–SOFC, H2 membranes, and advanced catalytic converters. Thin-film (∼5 μm) proton-conducting membranes with the nominal composition BaZr0.85Y0.15O3−δ (BZY) were prepared over porous Ni–8YSZ/Ni–BZY substrates by the solid-state reaction of a gastight 8YSZ layer and a coated BaCO3 layer. The resulting asymmetric membranes are of a homogeneous composition and are gastight. Indeed, XRD analysis showed a highly crystalline cubic perovskite. The solid-state reaction promoted the formation of (i) an electrolyte with very fine (∼100 nm) grains and high packing density and (ii) an unexpected porous needle-like top layer with a nominal composition similar to that of the protonic electrolyte, to which it is intimately attached. The layer morphology, phase distribution, and lattice composition were investigated by EDS–SEM, EDX as well as SIMS. Conduction properties of the protonic material were investigated by DC conductivity of pressed bars under different gas compositions and also by impedance spectroscopy of a supported thin film.
536 _ _ |0 G:(DE-Juel1)FUEK402
|2 G:(DE-HGF)
|a Rationelle Energieumwandlung
|c P12
|x 0
588 _ _ |a Dataset connected to Web of Science, Pubmed
700 1 _ |0 P:(DE-Juel1)129637
|a Meulenberg, W. A.
|b 1
|u FZJ
773 _ _ |0 PERI:(DE-600)2008170-4
|a 10.1111/j.1551-2916.2007.01677.x
|g Vol. 90, p. 2082 - 2089
|p 2082 - 2089
|q 90<2082 - 2089
|t Journal of the American Ceramic Society
|v 90
|x 0002-7820
|y 2007
856 7 _ |u http://dx.doi.org/10.1111/j.1551-2916.2007.01677.x
909 C O |o oai:juser.fz-juelich.de:56973
|p VDB
913 1 _ |0 G:(DE-Juel1)FUEK402
|b Energie
|k P12
|l Rationelle Energieumwandlung
|v Rationelle Energieumwandlung
|x 0
914 1 _ |y 2007
915 _ _ |0 StatID:(DE-HGF)0010
|a JCR/ISI refereed
920 1 _ |0 I:(DE-Juel1)VDB809
|d 30.09.2010
|g IEF
|k IEF-1
|l Werkstoffsynthese und Herstellungsverfahren
|x 0
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980 _ _ |a VDB
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980 _ _ |a journal
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980 _ _ |a UNRESTRICTED
981 _ _ |a I:(DE-Juel1)IMD-2-20101013
981 _ _ |a I:(DE-Juel1)IEK-1-20101013


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