001     57157
005     20190625111723.0
024 7 _ |2 pmid
|a pmid:17030463
024 7 _ |2 DOI
|a 10.1016/j.jconhyd.2006.08.002
024 7 _ |2 WOS
|a WOS:000243269800005
024 7 _ |a altmetric:21817196
|2 altmetric
037 _ _ |a PreJuSER-57157
041 _ _ |a eng
082 _ _ |a 550
084 _ _ |2 WoS
|a Environmental Sciences
084 _ _ |2 WoS
|a Geosciences, Multidisciplinary
084 _ _ |2 WoS
|a Water Resources
100 1 _ |a Wehrhan, A.
|b 0
|u FZJ
|0 P:(DE-Juel1)VDB36636
245 _ _ |a Transport of sulfadiazine in soil columns: Experiments and modelling approaches
260 _ _ |a Amsterdam [u.a.]
|b Elsevier Science
|c 2007
300 _ _ |a 107 - 135
336 7 _ |a Journal Article
|0 PUB:(DE-HGF)16
|2 PUB:(DE-HGF)
336 7 _ |a Output Types/Journal article
|2 DataCite
336 7 _ |a Journal Article
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336 7 _ |a ARTICLE
|2 BibTeX
336 7 _ |a JOURNAL_ARTICLE
|2 ORCID
336 7 _ |a article
|2 DRIVER
440 _ 0 |a Journal of Contaminant Hydrology
|x 0169-7722
|0 3225
|v 87
500 _ _ |a Record converted from VDB: 12.11.2012
520 _ _ |a Antibiotics, such as sulfadiazine, reach agricultural soils directly through manure of grazing livestock or indirectly through the spreading of manure or sewage sludge on the field. Knowledge about the fate of antibiotics in soils is crucial for assessing the environmental risk of these compounds, including possible transport to the groundwater. Transport of (14)C-labelled sulfadiazine was investigated in disturbed soil columns at a constant flow rate of 0.26 cm h(-1) near saturation. Sulfadiazine was applied in different concentrations for either a short or a long pulse duration. Breakthrough curves of sulfadiazine and the non-reactive tracer chloride were measured. At the end of the leaching period the soil concentration profiles were determined. The peak maxima of the breakthrough curves were delayed by a factor of 2 to 5 compared to chloride and the decreasing limbs are characterized by an extended tailing. However, the maximum relative concentrations differed as well as the eluted mass fractions, ranging from 18 to 83% after 500 h of leaching. To identify relevant sorption processes, breakthrough curves of sulfadiazine were fitted with a convective-dispersive transport model, considering different sorption concepts with one, two and three sorption sites. Breakthrough curves can be fitted best with a three-site sorption model, which includes two reversible kinetic and one irreversible sorption site. However, the simulated soil concentration profiles did not match the observations for all of the used models. Despite this incomplete process description, the obtained results have implications for the transport behavior of sulfadiazine in the field. Its leaching may be enhanced if it is frequently applied at higher concentrations.
536 _ _ |a Terrestrische Umwelt
|c P24
|2 G:(DE-HGF)
|0 G:(DE-Juel1)FUEK407
|x 0
588 _ _ |a Dataset connected to Web of Science, Pubmed
650 _ 2 |2 MeSH
|a Adsorption
650 _ 2 |2 MeSH
|a Chlorides: analysis
650 _ 2 |2 MeSH
|a Models, Biological
650 _ 2 |2 MeSH
|a Models, Theoretical
650 _ 2 |2 MeSH
|a Soil Pollutants: analysis
650 _ 2 |2 MeSH
|a Sulfadiazine: analysis
650 _ 2 |2 MeSH
|a Water Movements
650 _ 2 |2 MeSH
|a Water Pollutants, Chemical: analysis
650 _ 7 |0 0
|2 NLM Chemicals
|a Chlorides
650 _ 7 |0 0
|2 NLM Chemicals
|a Soil Pollutants
650 _ 7 |0 0
|2 NLM Chemicals
|a Water Pollutants, Chemical
650 _ 7 |0 68-35-9
|2 NLM Chemicals
|a Sulfadiazine
650 _ 7 |a J
|2 WoSType
653 2 0 |2 Author
|a sulfadiazine transport
653 2 0 |2 Author
|a antibiotics
653 2 0 |2 Author
|a soil column
653 2 0 |2 Author
|a breakthrough curve
653 2 0 |2 Author
|a transport models
653 2 0 |2 Author
|a sorption models
700 1 _ |a Kasteel, R.
|b 1
|u FZJ
|0 P:(DE-Juel1)VDB724
700 1 _ |a Simunek, J.
|b 2
|u FZJ
|0 P:(DE-Juel1)VDB57645
700 1 _ |a Groeneweg, J.
|b 3
|u FZJ
|0 P:(DE-Juel1)129462
700 1 _ |a Vereecken, H.
|b 4
|u FZJ
|0 P:(DE-Juel1)129549
773 _ _ |a 10.1016/j.jconhyd.2006.08.002
|g Vol. 89, p. 107 - 135
|p 107 - 135
|q 89<107 - 135
|0 PERI:(DE-600)1494766-3
|t Journal of contaminant hydrology
|v 89
|y 2007
|x 0169-7722
856 7 _ |u http://dx.doi.org/10.1016/j.jconhyd.2006.08.002
909 C O |o oai:juser.fz-juelich.de:57157
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|l Terrestrische Umwelt
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914 1 _ |y 2007
915 _ _ |0 StatID:(DE-HGF)0010
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920 1 _ |d 31.10.2010
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