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005     20180211161536.0
024 7 _ |2 DOI
|a 10.1016/j.jmmm.2006.02.103
024 7 _ |2 WOS
|a WOS:000240760800007
037 _ _ |a PreJuSER-57170
041 _ _ |a eng
082 _ _ |a 530
084 _ _ |2 WoS
|a Materials Science, Multidisciplinary
084 _ _ |2 WoS
|a Physics, Condensed Matter
100 1 _ |a Groudeva-Zotova, S.
|b 0
|0 P:(DE-HGF)0
245 _ _ |a Phase composition and magnetic characteristics of Fe-filled multi-walled carbon nanotubes
260 _ _ |a Amsterdam
|b North-Holland Publ. Co.
|c 2006
300 _ _ |a 40 - 50
336 7 _ |a Journal Article
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336 7 _ |a ARTICLE
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336 7 _ |a JOURNAL_ARTICLE
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336 7 _ |a article
|2 DRIVER
440 _ 0 |a Journal of Magnetism and Magnetic Materials
|x 0304-8853
|0 3490
|y 1
|v 306
500 _ _ |a Record converted from VDB: 12.11.2012
520 _ _ |a The work addresses the correlation between the phase composition and the magnetic characteristics of aligned Fe-filled multi-walled carbon nanotubes (Fe-MWCNTs) grown by pyrolysis of ferrocene on oxidized Si substrates. In a combinatorial approach we exploited the extremely high gradients of the technological parameters temperature and ferrocene flow across the surface of a substrate positioned close to the reactor wall to obtain a large variation in the structural and magnetic properties of the Fe-MWCNTs. In this way, we established several clear correlations between the Fe-filling phase composition and the overall magnetic characteristics of the aligned Fe-MWCNTs. The alpha-Fe rich samples, which possess a more ordered graphitic sheet structure, a higher degree of preferred crystalline orientation of the metal filling and much larger metal crystallites in comparison with the carbide-rich samples, show a much stronger magnetic anisotropy with easy axis perpendicular to the substrate and unusually high values of the coercive field H-c and the saturation field H-s. The changes in the measured saturation magnetisation M-s and the H-c values correlate well with the variation of the alpha-Fe content and the filling crystallinity. A special annealing treatment of the samples causes a distinct increase of the alpha-Fe quantity and an increase of the measured average grain size. The respective magnetic characteristics show a significant increase of the overall magnetic moment and decrease of the coercive field. The correlation between the structural and the magnetic characteristics of the annealed samples matches quite well the respective correlations in the case of as-deposited samples. (C) 2006 Elsevier B.V. All rights reserved.
536 _ _ |a Kondensierte Materie
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650 _ 7 |a J
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653 2 0 |2 Author
|a magnetic fibres
653 2 0 |2 Author
|a crystal structure
653 2 0 |2 Author
|a ferromagnetism
653 2 0 |2 Author
|a uniaxial anisotropy
700 1 _ |a Kozhuharova, R.
|b 1
|0 P:(DE-HGF)0
700 1 _ |a Elefant, D.
|b 2
|0 P:(DE-HGF)0
700 1 _ |a Mühl, T.
|b 3
|0 P:(DE-HGF)0
700 1 _ |a Schneider, C. M.
|b 4
|u FZJ
|0 P:(DE-Juel1)130948
700 1 _ |a Mönch, I.
|b 5
|0 P:(DE-HGF)0
773 _ _ |a 10.1016/j.jmmm.2006.02.103
|g Vol. 306, p. 40 - 50
|p 40 - 50
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|0 PERI:(DE-600)1479000-2
|t Journal of magnetism and magnetic materials
|v 306
|y 2006
|x 0304-8853
856 7 _ |u http://dx.doi.org/10.1016/j.jmmm.2006.02.103
909 C O |o oai:juser.fz-juelich.de:57170
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914 1 _ |a Nachtrag
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915 _ _ |0 StatID:(DE-HGF)0010
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920 1 _ |d 31.12.2006
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