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000057309 0247_ $$2DOI$$a10.1007/s11581-006-0028-0
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000057309 084__ $$2WoS$$aChemistry, Physical
000057309 084__ $$2WoS$$aElectrochemistry
000057309 084__ $$2WoS$$aPhysics, Condensed Matter
000057309 1001_ $$0P:(DE-Juel1)VDB3067$$aSchober, T.$$b0$$uFZJ
000057309 245__ $$aProton conductivity in silica gels
000057309 260__ $$aBerlin$$bSpringer$$c2006
000057309 300__ $$a131 - 134
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000057309 440_0 $$06984$$aIonics$$v12$$x0947-7047$$y2
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000057309 520__ $$aCommercial silica gel drying pearls were used in impedance measurements between ambient temperature and 300 degrees C in dry and humid atmospheres. A pronounced difference was seen supporting previous conclusions that proton conduction was operative in these amorphous samples. The same conclusion was reached on the basis of a fuel cell experiment at ambient temperature. A Nernst voltage close to the theoretical one was observed. Mechanical tests were carried out with silica gel plates made from the above material. Such plates displayed in the bending mode a time-dependent anelastic relaxation, i.e., a Gorsky effect, which arose from the long-range diffusion of protonic defects from the compressed to the dilated part of the plate. The chemical diffusivity and the density of the protonic defects could be determined. The same Gorsky effect may be expected in crystalline proton conductors, and also in Li-containing ceramics.
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000057309 650_7 $$2WoSType$$aJ
000057309 65320 $$2Author$$asilica gel
000057309 65320 $$2Author$$aNernst voltage
000057309 65320 $$2Author$$aGorsky effect
000057309 773__ $$0PERI:(DE-600)2226746-3$$a10.1007/s11581-006-0028-0$$gVol. 12, p. 131 - 134$$p131 - 134$$q12<131 - 134$$tIonics$$v12$$x0947-7047$$y2006
000057309 8567_ $$uhttp://dx.doi.org/10.1007/s11581-006-0028-0
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