TY - JOUR
AU - Yang, Y.
AU - Burkhardt, T. W.
AU - Gompper, G.
TI - Free energy and extension of a semiflexible polymer in cylindrical confining geometries
JO - Physical review / E
VL - 76
IS - 1
SN - 1539-3755
CY - College Park, Md.
PB - APS
M1 - PreJuSER-57335
SP - 011804
PY - 2007
N1 - Record converted from VDB: 12.11.2012
AB - We consider a long, semiflexible polymer with persistence length P and contour length L fluctuating in a narrow cylindrical channel of diameter D. In the regime D < P < L the free energy of confinement Delta F and the length of the channel R-parallel to occupied by the polymer are given by Odijk's relations Delta F/R-parallel to=A(o)k(B)TP(-1/3)D(-2/3) and R-parallel to=L[1-alpha(o)(D/P)(2/3)], where A(o) and alpha(o) are dimensionless amplitudes. Using a simulation algorithm inspired by the pruned enriched Rosenbluth method, which yields results for very long polymers, we determine A(o) and alpha(o) and the analogous amplitudes for a channel with a rectangular cross section. For a semiflexible polymer confined to the surface of a cylinder, the corresponding amplitudes are derived with an exact analytic approach. The results are relevant for interpreting experiments on biopolymers in microchannels or microfluidic devices.
KW - J (WoSType)
LB - PUB:(DE-HGF)16
UR - <Go to ISI:>//WOS:000248548900086
DO - DOI:10.1103/PhysRevE.76.011804
UR - https://juser.fz-juelich.de/record/57335
ER -