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@ARTICLE{Dorf:57451,
author = {Dorf, M. and Bösch, H. and Butz, A. and Camy-Peyret, C.
and Chipperfield, M. P. and Engel, A and Goutail, F. and
Grunow, K. and Hendrick, F. and Hrechanyy, S. and Naujokat,
B. and Pommereau, J. P. and van Roozendael, M. and Sioris,
C. and Stroh, F. and Weidner, F. and Pfeilsticker, K.},
title = {{B}alloon-borne stratospheric {B}r{O} measurements:
comparison with {E}nvisat/{SCIAMACHY} {B}r{O} limb profiles},
journal = {Atmospheric chemistry and physics},
volume = {6},
issn = {1680-7316},
address = {Katlenburg-Lindau},
publisher = {EGU},
reportid = {PreJuSER-57451},
pages = {2483 - 2501},
year = {2006},
note = {Record converted from VDB: 12.11.2012},
abstract = {For the first time, results of four stratospheric BrO
profiling instruments, are presented and compared with
reference to the SLIMCAT 3-dimensional chemical transport
model (3-D CTM). Model calculations are used to infer a BrO
profile validation set, measured by 3 different balloon
sensors, for the new Envisat/SCIAMACHY (ENVIronment
SATellite/SCanning Imaging Absorption spectroMeter for
Atmospheric CHartographY) satellite instrument. The balloon
observations include ( a) balloon-borne in situ resonance
fluorescence detection of BrO ( Triple), (b) balloon-borne
solar occultation DOAS measurements ( Differential Optical
Absorption Spectroscopy) of BrO in the UV, and ( c) BrO
profiling from the solar occultation SAOZ ( Systeme
d'Analyse par Observation Zenithale) balloon instrument.
Since stratospheric BrO is subject to considerable diurnal
variation and none of the measurements are performed close
enough in time and space for a direct comparison, all
balloon observations are considered with reference to
outputs from the 3-D CTM. The referencing is performed by
forward and backward air mass trajectory calculations to
match the balloon with the satellite observations. The
diurnal variation of BrO is considered by 1-D photochemical
model calculation along the trajectories. The 1-D
photochemical model is initialised with output data of the
3-D model with additional constraints on the vertical
transport, the total amount and photochemistry of
stratospheric bromine as given by the various balloon
observations. Total [Br-y]=(20.1 +/- 2.5) pptv obtained from
DOAS BrO observations at mid-latitudes in 2003, serves as an
upper limit of the comparison. Most of the balloon
observations agree with the photochemical model predictions
within their given error estimates. First retrieval
exercises of BrO limb profiling from the SCIAMACHY satellite
instrument on average agree to around $20\%$ with the
photochemically-corrected balloon observations of the remote
sensing instruments (SAOZ and DOAS). An exception is the in
situ Triple profile, in which the balloon and satellite data
mostly does not agree within the given errors. In general,
the satellite measurements show systematically higher values
below 25 km than the balloon data and a change in profile
shape above about 25 km.},
keywords = {J (WoSType)},
cin = {ICG-I},
ddc = {550},
cid = {I:(DE-Juel1)VDB47},
pnm = {Atmosphäre und Klima},
pid = {G:(DE-Juel1)FUEK406},
shelfmark = {Meteorology $\&$ Atmospheric Sciences},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000238675600010},
doi = {10.5194/acp-6-2483-2006},
url = {https://juser.fz-juelich.de/record/57451},
}