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@ARTICLE{Poppe:57544,
      author       = {Poppe, D. and Brauers, T. and Dorn, H.-P. and Karl, M. and
                      Mentel, T. and Schlosser, E. and Tillmann, R. and Wegener,
                      R. and Wahner, A.},
      title        = {{OH}-initiated degradation of several hydrocarbons in the
                      atmosphere simulation chamber {SAPHIR}},
      journal      = {Journal of atmospheric chemistry},
      volume       = {57},
      issn         = {0167-7764},
      address      = {Dordrecht [u.a.]},
      publisher    = {Springer Science + Business Media B.V},
      reportid     = {PreJuSER-57544},
      pages        = {203 - 214},
      year         = {2007},
      note         = {Record converted from VDB: 12.11.2012},
      abstract     = {Degradation of isoprene, m-xylene, n-octane, propene, and
                      methacrolein by hydroxyl radicals has been studied in the
                      simulation chamber SAPHIR under burden of trace gases as
                      they are typical for the moderately polluted planetary
                      boundary layer. Measured time series of the hydrocarbon
                      mixing ratios and the OH concentrations were used to
                      determine the rate constants. The hydrocarbons were measured
                      with gas chromatography and proton transfer reaction mass
                      spectrometry. OH was measured with the Julich DOAS
                      (differential optical absorption spectroscopy) instrument.
                      In all cases except methacrolein good agreement was found
                      with the reference rate constants taken from theMaster
                      Chemical Mechanism ( MCM3.1). The data for methacrolein are
                      consistent with the results of Karl et al. ( J. Atmos. Chem
                      55, 2006, doi:10.1007/s10874-006-9034-x) who reported a
                      $12\%$ smaller value. The degradation of hydrocarbons
                      provides an independent method to analyse precision and
                      accuracy of the OH measurements. A precision of better than
                      $4\%$ over a period of nearly 4 months was found. The
                      accuracy is within the limitations given by the light
                      absorption cross section of OH. Both results are consistent
                      with earlier results by Hausmann et al.},
      keywords     = {J (WoSType)},
      cin          = {ICG-2 / JARA-ENERGY / JARA-SIM},
      ddc          = {540},
      cid          = {I:(DE-Juel1)VDB791 / $I:(DE-82)080011_20140620$ /
                      I:(DE-Juel1)VDB1045},
      pnm          = {Atmosphäre und Klima},
      pid          = {G:(DE-Juel1)FUEK406},
      shelfmark    = {Environmental Sciences / Meteorology $\&$ Atmospheric
                      Sciences},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000248002200001},
      doi          = {10.1007/s10874-007-9065-y},
      url          = {https://juser.fz-juelich.de/record/57544},
}