001     57544
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024 7 _ |2 DOI
|a 10.1007/s10874-007-9065-y
024 7 _ |2 WOS
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037 _ _ |a PreJuSER-57544
041 _ _ |a eng
082 _ _ |a 540
084 _ _ |2 WoS
|a Environmental Sciences
084 _ _ |2 WoS
|a Meteorology & Atmospheric Sciences
100 1 _ |a Poppe, D.
|b 0
|u FZJ
|0 P:(DE-Juel1)16311
245 _ _ |a OH-initiated degradation of several hydrocarbons in the atmosphere simulation chamber SAPHIR
260 _ _ |a Dordrecht [u.a.]
|b Springer Science + Business Media B.V
|c 2007
300 _ _ |a 203 - 214
336 7 _ |a Journal Article
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440 _ 0 |a Journal of Atmospheric Chemistry
|x 0167-7764
|0 3073
|v 57
500 _ _ |a Record converted from VDB: 12.11.2012
520 _ _ |a Degradation of isoprene, m-xylene, n-octane, propene, and methacrolein by hydroxyl radicals has been studied in the simulation chamber SAPHIR under burden of trace gases as they are typical for the moderately polluted planetary boundary layer. Measured time series of the hydrocarbon mixing ratios and the OH concentrations were used to determine the rate constants. The hydrocarbons were measured with gas chromatography and proton transfer reaction mass spectrometry. OH was measured with the Julich DOAS (differential optical absorption spectroscopy) instrument. In all cases except methacrolein good agreement was found with the reference rate constants taken from theMaster Chemical Mechanism ( MCM3.1). The data for methacrolein are consistent with the results of Karl et al. ( J. Atmos. Chem 55, 2006, doi:10.1007/s10874-006-9034-x) who reported a 12% smaller value. The degradation of hydrocarbons provides an independent method to analyse precision and accuracy of the OH measurements. A precision of better than 4% over a period of nearly 4 months was found. The accuracy is within the limitations given by the light absorption cross section of OH. Both results are consistent with earlier results by Hausmann et al.
536 _ _ |a Atmosphäre und Klima
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653 2 0 |2 Author
|a atmospheric degradation of hydrocarbons
653 2 0 |2 Author
|a hydroxyl radicals
653 2 0 |2 Author
|a tropospheric ozone
653 2 0 |2 Author
|a n-octane
653 2 0 |2 Author
|a propene
653 2 0 |2 Author
|a m-xylene
653 2 0 |2 Author
|a isoprene
653 2 0 |2 Author
|a methacrolein
653 2 0 |2 Author
|a simulation chamber
653 2 0 |2 Author
|a measurement of atmospheric OH concentrations
700 1 _ |a Brauers, T.
|b 1
|u FZJ
|0 P:(DE-Juel1)16306
700 1 _ |a Dorn, H.-P.
|b 2
|u FZJ
|0 P:(DE-Juel1)16317
700 1 _ |a Karl, M.
|b 3
|u FZJ
|0 P:(DE-Juel1)VDB13401
700 1 _ |a Mentel, T.
|b 4
|u FZJ
|0 P:(DE-Juel1)16346
700 1 _ |a Schlosser, E.
|b 5
|u FZJ
|0 P:(DE-Juel1)VDB26256
700 1 _ |a Tillmann, R.
|b 6
|u FZJ
|0 P:(DE-Juel1)5344
700 1 _ |a Wegener, R.
|b 7
|u FZJ
|0 P:(DE-Juel1)2367
700 1 _ |a Wahner, A.
|b 8
|u FZJ
|0 P:(DE-Juel1)16324
773 _ _ |a 10.1007/s10874-007-9065-y
|g Vol. 57, p. 203 - 214
|p 203 - 214
|q 57<203 - 214
|0 PERI:(DE-600)1475524-5
|t Journal of atmospheric chemistry
|v 57
|y 2007
|x 0167-7764
856 7 _ |u http://dx.doi.org/10.1007/s10874-007-9065-y
909 C O |o oai:juser.fz-juelich.de:57544
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