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@ARTICLE{Lssem:57559,
      author       = {Lüssem, B. and Müller-Meskamp, B. and Karthäuser, S. and
                      Waser, R. and Homberger, M. and Simon, U.},
      title        = {{STM} study of mixed alkanethiol/biphenylthiol
                      self-assembled monolayers on {A}u(111)},
      journal      = {Langmuir},
      volume       = {22},
      number       = {7},
      issn         = {0743-7463},
      address      = {Washington, DC},
      publisher    = {ACS Publ.},
      reportid     = {PreJuSER-57559},
      pages        = {3021 - 3027},
      year         = {2006},
      note         = {Record converted from VDB: 12.11.2012},
      abstract     = {A method is presented for depositing mixed self-assembled
                      monolayers (SAMs) of dodecanethiol (C12) and
                      4'-methyl-1,1'-biphenyl-4-butane (H3C-C6H4-C6H4-(CH2)4-SH,
                      BP4) by insertion of BP4 into a closely packed SAM of
                      dodecanethiol on Au(111). Insertion takes place at defect
                      sites such as domain boundaries or etch pits in the gold
                      surface that are characteristic of C12 monolayers on gold.
                      With a lower probability, insertion also occurs beside
                      defect sites inside dodecanethiol domains. Insertion at
                      defect sites results in domains of BP4, whereas insertion
                      into C12 domains leads to isolated BP4 molecules. The
                      isolated BP4 molecules are shown not to move at room
                      temperature. By comparing the apparent height of the
                      isolated BP4 molecules and BP4 domains, it is proposed that
                      the isolated molecules have the same conformation as in the
                      full-coverage phase. A simple two-layer model is proposed to
                      characterize the current transport through BP4. The decay
                      constant beta for the phenylene groups is deduced from the
                      apparent STM heights of the inserted BP4 islands compared to
                      the STM heights of the C12 closely packed monolayers.},
      keywords     = {J (WoSType)},
      cin          = {IFF-IEM / JARA-FIT},
      ddc          = {670},
      cid          = {I:(DE-Juel1)VDB321 / $I:(DE-82)080009_20140620$},
      pnm          = {Kondensierte Materie},
      pid          = {G:(DE-Juel1)FUEK414},
      shelfmark    = {Chemistry, Multidisciplinary / Chemistry, Physical /
                      Materials Science, Multidisciplinary},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:16548552},
      UT           = {WOS:000236843300021},
      doi          = {10.1021/la052791u},
      url          = {https://juser.fz-juelich.de/record/57559},
}