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@ARTICLE{Sreeraj:57871,
      author       = {Sreeraj, P. and Wiemhöfer, H.-D. and Hoffmann, R.-D. and
                      Skowronek, R. and Kirfel, A. and Pöttgen, R.},
      title        = {{N}eutron diffraction and electrochemical studies on
                      {L}ilr{S}n4},
      journal      = {Journal of solid state chemistry},
      volume       = {179},
      issn         = {0022-4596},
      address      = {Orlando, Fla.},
      publisher    = {Academic Press},
      reportid     = {PreJuSER-57871},
      pages        = {355 - 361},
      year         = {2006},
      note         = {Record converted from VDB: 12.11.2012},
      abstract     = {Large quantities of single phase, polycrystalline LiIrSn4
                      have been synthesised from the elements by melting in sealed
                      tantalum tubes and subsequent annealing. LiIrSn4
                      crystallises with an ordered version of the PdGa5 structure:
                      I4/mcm, a = 655.62(8), c = 1128.6(2) pm. The lithium atoms
                      were clearly localised from a neutron powder diffraction
                      study: R-p = 0.147 and R-F = 0.058. Time-dependent
                      electrochemical polarisation techniques, i.e. coulometric
                      titration, chronopotentiometry, chronoamperometry and cyclic
                      voltammetry were used to study the kinetics of lithium ion
                      diffusion in this stannide. The range of homogeneity
                      (Li1+Delta delta IrSn4, -0.091 <= delta <= + 0.012) without
                      any structural change in the host structure and the chemical
                      diffusion coefficient (similar to 10(-7)-10(-9) cm(2)/s)
                      point out that LiIrSn4 is a first example of a large class
                      of intermetallic compounds with lithium and electron
                      mobility. Optimised materials from these ternary lithium
                      alloys may be potential electrode material for rechargeable
                      lithium batteries. (C) 2005 Elsevier Inc. All rights
                      reserved.},
      keywords     = {J (WoSType)},
      cin          = {IFF-ISM},
      ddc          = {540},
      cid          = {I:(DE-Juel1)VDB342},
      pnm          = {Kondensierte Materie},
      pid          = {G:(DE-Juel1)FUEK414},
      shelfmark    = {Chemistry, Inorganic $\&$ Nuclear / Chemistry, Physical},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000235282400003},
      doi          = {10.1016/j.jssc.2005.10.026},
      url          = {https://juser.fz-juelich.de/record/57871},
}