001     57871
005     20240529111552.0
024 7 _ |2 DOI
|a 10.1016/j.jssc.2005.10.026
024 7 _ |2 WOS
|a WOS:000235282400003
037 _ _ |a PreJuSER-57871
041 _ _ |a eng
082 _ _ |a 540
084 _ _ |2 WoS
|a Chemistry, Inorganic & Nuclear
084 _ _ |2 WoS
|a Chemistry, Physical
100 1 _ |a Sreeraj, P.
|b 0
|0 P:(DE-HGF)0
245 _ _ |a Neutron diffraction and electrochemical studies on LilrSn4
260 _ _ |a Orlando, Fla.
|b Academic Press
|c 2006
300 _ _ |a 355 - 361
336 7 _ |a Journal Article
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336 7 _ |a ARTICLE
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336 7 _ |a JOURNAL_ARTICLE
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336 7 _ |a article
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440 _ 0 |a Journal of Solid State Chemistry
|x 0022-4596
|0 8041
|y 2
|v 179
500 _ _ |a Record converted from VDB: 12.11.2012
520 _ _ |a Large quantities of single phase, polycrystalline LiIrSn4 have been synthesised from the elements by melting in sealed tantalum tubes and subsequent annealing. LiIrSn4 crystallises with an ordered version of the PdGa5 structure: I4/mcm, a = 655.62(8), c = 1128.6(2) pm. The lithium atoms were clearly localised from a neutron powder diffraction study: R-p = 0.147 and R-F = 0.058. Time-dependent electrochemical polarisation techniques, i.e. coulometric titration, chronopotentiometry, chronoamperometry and cyclic voltammetry were used to study the kinetics of lithium ion diffusion in this stannide. The range of homogeneity (Li1+Delta delta IrSn4, -0.091 <= delta <= + 0.012) without any structural change in the host structure and the chemical diffusion coefficient (similar to 10(-7)-10(-9) cm(2)/s) point out that LiIrSn4 is a first example of a large class of intermetallic compounds with lithium and electron mobility. Optimised materials from these ternary lithium alloys may be potential electrode material for rechargeable lithium batteries. (C) 2005 Elsevier Inc. All rights reserved.
536 _ _ |a Kondensierte Materie
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653 2 0 |2 Author
|a intermetallic compound
653 2 0 |2 Author
|a electrochemistry
653 2 0 |2 Author
|a ionic conductivity
700 1 _ |a Wiemhöfer, H.-D.
|b 1
|0 P:(DE-HGF)0
700 1 _ |a Hoffmann, R.-D.
|b 2
|0 P:(DE-HGF)0
700 1 _ |a Skowronek, R.
|b 3
|u FZJ
|0 P:(DE-Juel1)VDB59998
700 1 _ |a Kirfel, A.
|b 4
|0 P:(DE-HGF)0
700 1 _ |a Pöttgen, R.
|b 5
|0 P:(DE-HGF)0
773 _ _ |a 10.1016/j.jssc.2005.10.026
|g Vol. 179, p. 355 - 361
|p 355 - 361
|q 179<355 - 361
|0 PERI:(DE-600)1469806-7
|t Journal of solid state chemistry
|v 179
|y 2006
|x 0022-4596
856 7 _ |u http://dx.doi.org/10.1016/j.jssc.2005.10.026
909 C O |o oai:juser.fz-juelich.de:57871
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914 1 _ |a Nachtrag
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981 _ _ |a I:(DE-Juel1)JCNS-2-20110106
981 _ _ |a I:(DE-Juel1)PGI-4-20110106


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