% IMPORTANT: The following is UTF-8 encoded. This means that in the presence
% of non-ASCII characters, it will not work with BibTeX 0.99 or older.
% Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or
% “biber”.
@ARTICLE{Schofield:57887,
author = {Schofield, R. and Frieler, K. and Wohltmann, I. and Rex, M.
and von Hobe, M. and Stroh, F. and Koch, G. and Peter, T.
and Canty, R. and Salawitch, R. and Volk, C. M.},
title = {{P}olar stratospheric chlorine kinetics from a self-match
flight during {SOLVE}-{II}/{EUPLEX}},
journal = {Geophysical research letters},
volume = {35},
issn = {0094-8276},
address = {Washington, DC},
publisher = {American Geophysical Union},
reportid = {PreJuSER-57887},
pages = {L01807},
year = {2008},
note = {Record converted from VDB: 12.11.2012},
abstract = {In-situ measurements of ClO made onboard the Geophysica
aircraft on 30 January 2003 in the Arctic afford a novel
approach to constrain the kinetic parameters governing polar
stratospheric chlorine chemistry using atmospheric
observations. The self-match flight pattern, i.e.sampling
individual air masses twice at different zenith angles, was
utilized by simulating the evolution of ClO mixing ratios
between two 'matching' points using a photochemical model
and optimizing the model parameters to fit the observations
within a retrieval framework. Our results suggest a
ClO/ClOOCl thermal equilibrium constant K-eq a factor of 5
smaller and a ratio J/k(f) a factor of 2 larger than the
values based on the JPL recommendations. This concurs with
other studies based on observed ClOx partitioning and
corroborates that our understanding of stratospheric
chlorine chemistry is incomplete, particularly in the light
of the most recent laboratory experiments pointing to a
J/k(f) ratio almost an order of magnitude below the JPL
recommendation.},
keywords = {J (WoSType)},
cin = {ICG-1},
ddc = {550},
cid = {I:(DE-Juel1)VDB790},
pnm = {Atmosphäre und Klima},
pid = {G:(DE-Juel1)FUEK406},
shelfmark = {Geosciences, Multidisciplinary},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000252362000001},
doi = {10.1029/2007GL031740},
url = {https://juser.fz-juelich.de/record/57887},
}