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@ARTICLE{Hara:58662,
      author       = {Hara, M. and Linke, U. and Wandlowski, Th.},
      title        = {{P}reparation and {E}lectrochemical {C}haracterization of
                      {P}alladium {S}ingle {C}rystal {E}lectrodes in 0.1 {M}
                      {H}2{SO}4 and 0.1 {M} {HC}l{O}4 - {L}ow {I}ndex phases},
      journal      = {Electrochimica acta},
      volume       = {52},
      issn         = {0013-4686},
      address      = {New York, NY [u.a.]},
      publisher    = {Elsevier},
      reportid     = {PreJuSER-58662},
      pages        = {5733 - 5748},
      year         = {2007},
      note         = {Record converted from VDB: 12.11.2012},
      abstract     = {The electrochemical properties of Pd(1 1 1), Pd(1 0 0) and
                      Pd(1 1 0) single crystal bead electrodes, prepared by a
                      novel electron beam heating and inductive annealing
                      technique, have been characterized in 0.1 M sulfuric acid
                      and 0.1 M perchloric acid by cyclic voltammetry and
                      chronoamperometry. Hydrogen and (hydrogen) sulfate
                      adsorption as well as surface oxidation were found to depend
                      strongly on the crystallographic orientation and the nature
                      of the electrolyte. The combination of charge displacement
                      and voltammetric experiments allowed the determination of
                      the potentials of zero total charge (E-pztc) of Pd(1 1 1)
                      and Pd(1 0 0). The values of E-pztc in sulfuric acid were
                      found to be more negative than in perchloric acid. The
                      estimation of E-pztc for Pd(1 1 0) was hampered by the
                      superposition with hydrogen absorption. The
                      electro-oxidation of irreversible adsorbed carbon monoxide
                      monolayers was studied on the three low-index Pd electrodes.
                      The onset potential of the CO oxidation reaction follows the
                      sequence Pd(1 0 0) < Pd(1 1 0) < Pd(1 1 1).
                      Chronoamperometric experiments revealed a pronounced
                      structure sensitivity of the reaction kinetics. The
                      processes involved are determined by nucleation of
                      oxygen-containing species on defect (step) sites and by slow
                      diffusion of COads on (1 1 1) terrace sites. (c) 2006
                      Elsevier Ltd. All rights reserved.},
      keywords     = {J (WoSType)},
      cin          = {CNI / IBN-3 / JARA-FIT},
      ddc          = {540},
      cid          = {I:(DE-Juel1)VDB381 / I:(DE-Juel1)VDB801 /
                      $I:(DE-82)080009_20140620$},
      pnm          = {Grundlagen für zukünftige Informationstechnologien},
      pid          = {G:(DE-Juel1)FUEK412},
      shelfmark    = {Electrochemistry},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000246655300027},
      doi          = {10.1016/j.electacta.2006.11.048},
      url          = {https://juser.fz-juelich.de/record/58662},
}