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| Hauptseite > Publikationsdatenbank > Scanning Tunneling Microscopy and Spectroscopy Studies of w-(4'-methyl-biphenyl-4-yl) alkanthiols on Au(111)-(1x1) Electrodes > print |
| Hauptseite > Publikationsdatenbank > Scanning Tunneling Microscopy and Spectroscopy Studies of w-(4'-methyl-biphenyl-4-yl) alkanthiols on Au(111)-(1x1) Electrodes > print |
| 001 | 58665 | ||
| 005 | 20180211174811.0 | ||
| 024 | 7 | _ | |2 pmid |a pmid:17476662 |
| 024 | 7 | _ | |2 DOI |a 10.1002/cphc.200600781 |
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| 037 | _ | _ | |a PreJuSER-58665 |
| 041 | _ | _ | |a eng |
| 082 | _ | _ | |a 540 |
| 084 | _ | _ | |2 WoS |a Chemistry, Physical |
| 084 | _ | _ | |2 WoS |a Physics, Atomic, Molecular & Chemical |
| 100 | 1 | _ | |a Su, G.J. |b 0 |u FZJ |0 P:(DE-Juel1)VDB71221 |
| 245 | _ | _ | |a Scanning Tunneling Microscopy and Spectroscopy Studies of w-(4'-methyl-biphenyl-4-yl) alkanthiols on Au(111)-(1x1) Electrodes |
| 260 | _ | _ | |a Weinheim |b Wiley-VCH Verl. |c 2007 |
| 300 | _ | _ | |a 1037 |
| 336 | 7 | _ | |a Journal Article |0 PUB:(DE-HGF)16 |2 PUB:(DE-HGF) |
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| 336 | 7 | _ | |a article |2 DRIVER |
| 440 | _ | 0 | |a ChemPhysChem |x 1439-4235 |0 10582 |v 8 |
| 500 | _ | _ | |a Record converted from VDB: 12.11.2012 |
| 520 | _ | _ | |a 4-methyl-4'-(n-mercaptoalkyl)biphenyl (CH3-C6H4-C6H4-(CH2)n-SH, n=3-6, BPn) monolayers assembled on Au(111)-(1x1) in 1,3,5,-trimethylbenzene (TMB) at various temperatures are studied by scanning tunneling microscopy (STM) and scanning tunneling spectroscopy (STS). High resolution STM images reveal that BP3 and BP5 form a (sqrt 3x2sqrt 3) repeating motif superimposed on a temperature-dependent Moire pattern. BP4 and BP6 adlayers are characterized by a coexisting (2sqrt 3x5sqrt 3) majority phase and a temperature-dependent (3xpsqrt 3) minority phase. Assembly at 60 degrees C or 90 degrees C leads to p=5. Compression of the adlayer was found at higher temperatures. Combined with high-resolution structure experiments, the electronic characteristics of BP3 and BP4 self-assembled monolayers (SAMs) were studied by monitoring current-distance (iT-Deltaz) and current-voltage (iT-Ebias) characteristics in TMB employing a gold STM tip|BPn|Au(111)-(1x1) configuration. The semilogarithmic (iT-Deltaz) plots yielded three linear regions in the range 10 pA |
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| 650 | _ | 7 | |a J |2 WoSType |
| 653 | 2 | 0 | |2 Author |a monolayers |
| 653 | 2 | 0 | |2 Author |a n-(mercaptoalkyl)biphenyls |
| 653 | 2 | 0 | |2 Author |a scanning probe microscopy |
| 653 | 2 | 0 | |2 Author |a self-assembly |
| 653 | 2 | 0 | |2 Author |a surface chemistry |
| 700 | 1 | _ | |a Aguilar-Sanchez, R. |b 1 |u FZJ |0 P:(DE-Juel1)VDB57077 |
| 700 | 1 | _ | |a Li, Z. |b 2 |u FZJ |0 P:(DE-Juel1)VDB2436 |
| 700 | 1 | _ | |a Pobelov, I. |b 3 |u FZJ |0 P:(DE-Juel1)VDB45469 |
| 700 | 1 | _ | |a Homberger, M. |b 4 |0 P:(DE-HGF)0 |
| 700 | 1 | _ | |a Simon, U. |b 5 |0 P:(DE-HGF)0 |
| 700 | 1 | _ | |a Wandlowski, Th. |b 6 |u FZJ |0 P:(DE-Juel1)VDB9859 |
| 773 | _ | _ | |a 10.1002/cphc.200600781 |g Vol. 8, p. 1037 |p 1037 |q 8<1037 |0 PERI:(DE-600)2025223-7 |t ChemPhysChem |v 8 |y 2007 |x 1439-4235 |
| 856 | 7 | _ | |u http://dx.doi.org/10.1002/cphc.200600781 |
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