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@ARTICLE{Ueba:59030,
      author       = {Ueba, H. and Persson, B. N. J.},
      title        = {{A}ction spectroscopy for single-molecule motion induced by
                      vibrational excitation with a scanning tunneling microscope},
      journal      = {Physical review / B},
      volume       = {75},
      number       = {4},
      issn         = {1098-0121},
      address      = {College Park, Md.},
      publisher    = {APS},
      reportid     = {PreJuSER-59030},
      pages        = {041403},
      year         = {2007},
      note         = {Record converted from VDB: 12.11.2012},
      abstract     = {We propose an action spectroscopy for single-molecule
                      motion induced by vibrational excitation with a scanning
                      tunneling microscope (STM). Calculations of the inelastic
                      tunneling current for excitation of the C-O stretch mode of
                      the CO molecule on metal surfaces are combined with a theory
                      which describes how the energy in the vibrational mode is
                      transferred to a reaction coordinate mode to overcome the
                      activation barrier. The calculated rate for CO hopping on Pd
                      (110) as a function of the bias voltage agrees with the
                      experimental result. It is proposed that the second
                      derivative of the reaction rate with respect to the bias
                      voltage is related to the vibrational density of states,
                      which usually cannot be directly observed in STM inelastic
                      electron tunneling spectroscopy when a molecule motion is
                      induced by vibrational excitation.},
      keywords     = {J (WoSType)},
      cin          = {IFF-1},
      ddc          = {530},
      cid          = {I:(DE-Juel1)VDB781},
      pnm          = {Kondensierte Materie},
      pid          = {G:(DE-Juel1)FUEK414},
      shelfmark    = {Physics, Condensed Matter},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000243895600015},
      doi          = {10.1103/PhysRevB.75.041403},
      url          = {https://juser.fz-juelich.de/record/59030},
}