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@ARTICLE{Wittlich:60128,
author = {Wittlich, M. and Koenig, B. W. and Hoffmann, S. and
Willbold, D.},
title = {{S}tructural characterisation of the transmembrane and
cytoplasmic domains of human {CD}4},
journal = {Biochimica et biophysica acta / Biomembranes},
volume = {1768},
issn = {0005-2736},
address = {Amsterdam},
publisher = {Elsevier},
reportid = {PreJuSER-60128},
pages = {2949 - 2960},
year = {2007},
note = {Record converted from VDB: 12.11.2012},
abstract = {Cluster determinant 4 (CD4) is a type I transmembrane
glycoprotein of 58 kDa. It consists of an extracellular
domain of 370 amino acids, a short transmembrane region, and
a cytoplasmic domain of 40 amino acids at the C-terminal
end. We investigated the structure of the 62 C-terminal
residues of CD4, comprising its transmembrane and
cytoplasmic domains. The five cysteine residues of this
region have been replaced with serine and histidine residues
in the polypeptide CD4mut. Uniformly 15N and 13C labeled
protein was recombinantly expressed in E. coli and purified.
Functional binding activity of CD4mut to protein VpU of the
human immunodeficiency virus type 1 (HIV-1) was verified.
Close to complete NMR resonance assignment of the 1H, 13C,
and 15N spins of CD4mut was accomplished. The secondary
structure of CD4mut in membrane simulating
dodecylphosphocholine (DPC) micelles was characterized based
on secondary chemical shift analysis, NOE-based
proton-proton distances, and circular dichroism
spectroscopy. A stable transmembrane helix and a short
amphipathic helix in the cytoplasmic region were identified.
The fractional helicity of the cytoplasmic helix appears to
be stabilized in the presence of DPC micelles, although the
extension of this helix is reduced in comparison to previous
studies on synthetic peptides in aqueous solution. The role
of the amphipathic helix and its potentially variable length
is discussed with respect to the biological functions of
CD4.},
keywords = {Amino Acid Sequence / Antigens, CD4: chemistry / Antigens,
CD4: genetics / Antigens, CD4: metabolism / Carbon Isotopes
/ Circular Dichroism / Human Immunodeficiency Virus
Proteins: metabolism / Humans / Magnetic Resonance
Spectroscopy: methods / Models, Molecular / Molecular
Sequence Data / Mutation / Nitrogen Isotopes / Protein
Binding / Protein Structure, Secondary / Protein Structure,
Tertiary / Viral Regulatory and Accessory Proteins:
metabolism / Antigens, CD4 (NLM Chemicals) / Carbon Isotopes
(NLM Chemicals) / Human Immunodeficiency Virus Proteins (NLM
Chemicals) / Nitrogen Isotopes (NLM Chemicals) / Viral
Regulatory and Accessory Proteins (NLM Chemicals) / J
(WoSType)},
cin = {INB-2 / JARA-SIM},
ddc = {570},
cid = {I:(DE-Juel1)VDB805 / I:(DE-Juel1)VDB1045},
pnm = {Funktion und Dysfunktion des Nervensystems},
pid = {G:(DE-Juel1)FUEK409},
shelfmark = {Biochemistry $\&$ Molecular Biology / Biophysics},
typ = {PUB:(DE-HGF)16},
pubmed = {pmid:18035040},
UT = {WOS:000252488900002},
doi = {10.1016/j.bbamem.2007.10.023},
url = {https://juser.fz-juelich.de/record/60128},
}