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000060364 041__ $$aeng
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000060364 084__ $$2WoS$$aChemistry, Organic
000060364 1001_ $$0P:(DE-HGF)0$$aSonwa, M.M.$$b0
000060364 245__ $$aDehydrogenation of ocimene by active carbon: artefact formation during headspace sampling from leaves of Phaseolus lunatus
000060364 260__ $$aZurich$$bARKAT$$c2007
000060364 300__ $$a164 - 172
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000060364 440_0 $$018241$$aArkivoc : free online journal of organic chemistry$$v$$x1551-7012$$y3
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000060364 520__ $$aThe blend of volatiles emitted from jasmonate-treated Lima bean ( Phaseolus lunatus) leaves comprised two ocimene-derived artefacts that were only present, if the compounds were collected on active carbon traps. Identified were (3E, 5E)-2,6-dimethyl-3,5,7-octatrien-2-ol ( 6) and ( 3E, 5E)-2,6-dimethyl- 1,3,5,7-octatetraene ( 5) resulting from oxidation of ocimene ( 2) by active carbon in presence of humid air. The catalytical capacity of the active carbon could be exploited for a rapid and efficient functionalization of ocimene to give the ( 3E, 5E)-2-alkoxy3,5,7-octatrienes ( 14), ( 15), and ( 16) in methanol, ethanol, or isopropanol as solvents.
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000060364 650_7 $$2WoSType$$aJ
000060364 65320 $$2Author$$aPhaseolus lunatus
000060364 65320 $$2Author$$aactive carbon
000060364 65320 $$2Author$$ainduced volatiles
000060364 65320 $$2Author$$aocimene
000060364 65320 $$2Author$$aclosed-loop-stripping
000060364 65320 $$2Author$$aanalysis (CLSA)
000060364 65320 $$2Author$$aSPME
000060364 7001_ $$0P:(DE-Juel1)VDB72929$$aBiedermann, A.$$b1$$uFZJ
000060364 7001_ $$0P:(DE-Juel1)2367$$aWegener, R.$$b2$$uFZJ
000060364 7001_ $$0P:(DE-HGF)0$$aSchulz, S.$$b3
000060364 7001_ $$0P:(DE-HGF)0$$aBoland, W.$$b4
000060364 773__ $$0PERI:(DE-600)2035084-3$$gp. 164 - 172$$p164 - 172$$q164 - 172$$tArkivoc$$x1551-7012$$y2007
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000060364 9141_ $$y2007
000060364 915__ $$0StatID:(DE-HGF)0020$$aNo peer review
000060364 9201_ $$0I:(DE-Juel1)VDB791$$d30.09.2010$$gICG$$kICG-2$$lTroposphäre$$x1
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