TY  - JOUR
AU  - Sonwa, M.M.
AU  - Biedermann, A.
AU  - Wegener, R.
AU  - Schulz, S.
AU  - Boland, W.
TI  - Dehydrogenation of ocimene by active carbon: artefact formation during headspace sampling from leaves of Phaseolus lunatus
JO  - Arkivoc
SN  - 1551-7012
CY  - Zurich
PB  - ARKAT
M1  - PreJuSER-60364
SP  - 164 - 172
PY  - 2007
N1  - Record converted from VDB: 12.11.2012
AB  - The blend of volatiles emitted from jasmonate-treated Lima bean ( Phaseolus lunatus) leaves comprised two ocimene-derived artefacts that were only present, if the compounds were collected on active carbon traps. Identified were (3E, 5E)-2,6-dimethyl-3,5,7-octatrien-2-ol ( 6) and ( 3E, 5E)-2,6-dimethyl- 1,3,5,7-octatetraene ( 5) resulting from oxidation of ocimene ( 2) by active carbon in presence of humid air. The catalytical capacity of the active carbon could be exploited for a rapid and efficient functionalization of ocimene to give the ( 3E, 5E)-2-alkoxy3,5,7-octatrienes ( 14), ( 15), and ( 16) in methanol, ethanol, or isopropanol as solvents.
KW  - J (WoSType)
LB  - PUB:(DE-HGF)16
UR  - <Go to ISI:>//WOS:000249059000015
UR  - https://juser.fz-juelich.de/record/60364
ER  -