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@ARTICLE{Sonwa:60364,
author = {Sonwa, M.M. and Biedermann, A. and Wegener, R. and Schulz,
S. and Boland, W.},
title = {{D}ehydrogenation of ocimene by active carbon: artefact
formation during headspace sampling from leaves of
{P}haseolus lunatus},
journal = {Arkivoc},
issn = {1551-7012},
address = {Zurich},
publisher = {ARKAT},
reportid = {PreJuSER-60364},
pages = {164 - 172},
year = {2007},
note = {Record converted from VDB: 12.11.2012},
abstract = {The blend of volatiles emitted from jasmonate-treated Lima
bean ( Phaseolus lunatus) leaves comprised two
ocimene-derived artefacts that were only present, if the
compounds were collected on active carbon traps. Identified
were (3E, 5E)-2,6-dimethyl-3,5,7-octatrien-2-ol ( 6) and (
3E, 5E)-2,6-dimethyl- 1,3,5,7-octatetraene ( 5) resulting
from oxidation of ocimene ( 2) by active carbon in presence
of humid air. The catalytical capacity of the active carbon
could be exploited for a rapid and efficient
functionalization of ocimene to give the ( 3E,
5E)-2-alkoxy3,5,7-octatrienes ( 14), ( 15), and ( 16) in
methanol, ethanol, or isopropanol as solvents.},
keywords = {J (WoSType)},
cin = {ICG-2},
ddc = {540},
cid = {I:(DE-Juel1)VDB791},
pnm = {Atmosphäre und Klima},
pid = {G:(DE-Juel1)FUEK406},
shelfmark = {Chemistry, Organic},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000249059000015},
url = {https://juser.fz-juelich.de/record/60364},
}