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000060717 084__ $$2WoS$$aChemistry, Physical
000060717 084__ $$2WoS$$aPhysics, Condensed Matter
000060717 1001_ $$0P:(DE-HGF)0$$aHenze, S. K. M.$$b0
000060717 245__ $$aVertical bonding distances of PTCDA on Au(111) and Ag(111): Relation to the bonding type
000060717 260__ $$aAmsterdam$$bElsevier$$c2007
000060717 300__ $$a1566 - 1573
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000060717 520__ $$aThe vertical bonding distance of 3,4,9,10-perylene-tetracarboxylic-dianhydride (PTCDA) above the Au(111) surface has been measured by the normal incidence X-ray standing wave (NIXSW) technique. The carbon skeleton of PTCDA has a vertical distance of D = (3.27 +/- 0.02) angstrom to the Au(111) substrate. This distance corresponds very nearly to the sum of the van der Waals radii of carbon and gold, suggesting the adsorption to be a physisorptive one. In contrast, the PTCDA/Ag(111) interface which according to spectroscopic data follows the standard model of chemisorption very closely, shows a considerably smaller bonding distance of D = (2.86 +/- 0.01) angstrom [A. Hauschild, K. Karki, B.C.C. Cowie, M. Rolilting, F.S. Tautz, M. Sokolowski, Phys. Rev. Lett. 94 (2005) 036106, comment: Rurali et al., Phys. Lett. 95 (2005) 209205, reply: Phys. Rev. Lett. 95 (2005) 209206]. The different vertical adsorption heights of PTCDA on gold and silver are discussed in relation to the different bonding mechanisms on both noble metal surfaces. (c) 2007 Elsevier B.V. All rights reserved.
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000060717 65320 $$2Author$$anormal incidence X-ray standing wave (NIXSW)
000060717 65320 $$2Author$$aPTCDA
000060717 65320 $$2Author$$aAu(111)
000060717 65320 $$2Author$$aAg(111)
000060717 65320 $$2Author$$achemisorption
000060717 65320 $$2Author$$aphysisorption
000060717 65320 $$2Author$$asurface structure
000060717 65320 $$2Author$$ametal-organic interface
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000060717 7001_ $$0P:(DE-HGF)0$$aBauer, O.$$b1
000060717 7001_ $$0P:(DE-HGF)0$$aLee, T.L.$$b2
000060717 7001_ $$0P:(DE-HGF)0$$aSokolowski, M.$$b3
000060717 7001_ $$0P:(DE-Juel1)128791$$aTautz, F. S.$$b4$$uFZJ
000060717 773__ $$0PERI:(DE-600)1479030-0$$a10.1016/j.susc.2007.01.020$$gVol. 601, p. 1566 - 1573$$p1566 - 1573$$q601<1566 - 1573$$tSurface science$$v601$$x0039-6028$$y2007
000060717 8567_ $$uhttp://dx.doi.org/10.1016/j.susc.2007.01.020
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