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@ARTICLE{Henze:60717,
author = {Henze, S. K. M. and Bauer, O. and Lee, T.L. and Sokolowski,
M. and Tautz, F. S.},
title = {{V}ertical bonding distances of {PTCDA} on {A}u(111) and
{A}g(111): {R}elation to the bonding type},
journal = {Surface science},
volume = {601},
issn = {0039-6028},
address = {Amsterdam},
publisher = {Elsevier},
reportid = {PreJuSER-60717},
pages = {1566 - 1573},
year = {2007},
note = {Record converted from VDB: 12.11.2012},
abstract = {The vertical bonding distance of
3,4,9,10-perylene-tetracarboxylic-dianhydride (PTCDA) above
the Au(111) surface has been measured by the normal
incidence X-ray standing wave (NIXSW) technique. The carbon
skeleton of PTCDA has a vertical distance of D = (3.27 +/-
0.02) angstrom to the Au(111) substrate. This distance
corresponds very nearly to the sum of the van der Waals
radii of carbon and gold, suggesting the adsorption to be a
physisorptive one. In contrast, the PTCDA/Ag(111) interface
which according to spectroscopic data follows the standard
model of chemisorption very closely, shows a considerably
smaller bonding distance of D = (2.86 +/- 0.01) angstrom [A.
Hauschild, K. Karki, B.C.C. Cowie, M. Rolilting, F.S. Tautz,
M. Sokolowski, Phys. Rev. Lett. 94 (2005) 036106, comment:
Rurali et al., Phys. Lett. 95 (2005) 209205, reply: Phys.
Rev. Lett. 95 (2005) 209206]. The different vertical
adsorption heights of PTCDA on gold and silver are discussed
in relation to the different bonding mechanisms on both
noble metal surfaces. (c) 2007 Elsevier B.V. All rights
reserved.},
keywords = {J (WoSType)},
cin = {IBN-3 / CNI / JARA-FIT},
ddc = {540},
cid = {I:(DE-Juel1)VDB801 / I:(DE-Juel1)VDB381 /
$I:(DE-82)080009_20140620$},
pnm = {Grundlagen für zukünftige Informationstechnologien},
pid = {G:(DE-Juel1)FUEK412},
shelfmark = {Chemistry, Physical / Physics, Condensed Matter},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000245616400019},
doi = {10.1016/j.susc.2007.01.020},
url = {https://juser.fz-juelich.de/record/60717},
}