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@ARTICLE{Tautz:60720,
      author       = {Tautz, F. S.},
      title        = {{S}tructure and bonding of large aromatic molecules on
                      noble metal surfaces: {T}he example of {PTCDA}},
      journal      = {Progress in surface science},
      volume       = {82},
      issn         = {0079-6816},
      address      = {Amsterdam [u.a.]},
      publisher    = {Elsevier},
      reportid     = {PreJuSER-60720},
      year         = {2007},
      note         = {Record converted from VDB: 12.11.2012},
      abstract     = {Recent efforts to understand the interaction of large
                      aromatic molecules with metal surfaces are discussed. We
                      focus exclusively on work involving the model molecule
                      3,4,9,10-perylene-tetracarboxylic-dianhydride (PTCDA) and
                      the noble metal surfaces of Cu, Ag, and Au. Using this
                      material system as an example, salient features of the
                      (chemical) bond between an extended pi-conjugated electron
                      system and a metallic substrate are illustrated. Interface
                      structures are a valuable indicator of the metal-molecule
                      interaction strength. Consistent with the trend observed for
                      small molecule adsorption, they indicate that the
                      interaction strength of PTCDA with the metal substrate
                      decreases in the order Cu-Ag-Au. The interfaces of PTCDA
                      with the Au(111) and Ag(111) surfaces have been studied in
                      particular detail. The interaction of Au(111) with PTCDA is
                      weak, leading to point-on-line coincidence between the
                      lattices of the substrate and the molecular overlayer.
                      Experimental results on this surface are generally
                      consistent with a predominantly physisorptive bonding of
                      PTCDA. The situation is different on Ag surfaces, and in
                      particular on Ag(111), where clear signs of PTCDA
                      chemisorption are observed in many ensemble averaging and
                      single molecule spectroscopies. Issues of electronic and
                      geometric structure as well as electron-vibron interaction,
                      and their relation to the chemical molecule-substrate
                      interaction, are discussed in detail. (c) 2007 Elsevier Ltd.
                      All rights reserved.},
      keywords     = {J (WoSType)},
      cin          = {IBN-3 / CNI / JARA-FIT},
      ddc          = {550},
      cid          = {I:(DE-Juel1)VDB801 / I:(DE-Juel1)VDB381 /
                      $I:(DE-82)080009_20140620$},
      pnm          = {Grundlagen für zukünftige Informationstechnologien},
      pid          = {G:(DE-Juel1)FUEK412},
      shelfmark    = {Chemistry, Physical / Physics, Condensed Matter},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000251752500001},
      doi          = {10.1016/j.progsurf.2007.09.001},
      url          = {https://juser.fz-juelich.de/record/60720},
}