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@ARTICLE{Armstrong:61830,
author = {Armstrong, B. D. and Lingwood, M.D. and McCarney, E.R. and
Brown, E.R. and Blümler, P. and Han, S.},
title = {{P}ortable {X}-band system for solution state dynamic
nuclear polarization},
journal = {Journal of magnetic resonance},
volume = {191},
issn = {1090-7807},
address = {Amsterdam [u.a.]},
publisher = {Elsevier},
reportid = {PreJuSER-61830},
pages = {273 - 281},
year = {2008},
note = {Record converted from VDB: 12.11.2012},
abstract = {This paper concerns instrumental approaches to obtain large
dynamic nuclear polarization (DNP) enhancements in a
completely portable system. We show that at fields of 0.35 T
under ambient conditions and at X-band frequencies, 1H
enhancements of >100-fold can be achieved using nitroxide
radical systems, which is near the theoretical maximum for
1H polarization using the Overhauser effect at this field.
These large enhancements were obtained using a custom built
microwave transmitter and a commercial TE102 X-band resonant
cavity. The custom built microwave transmitter is compact,
so when combined with a permanent magnet it is readily
transportable. Our commercial X-band resonator was modified
to be tunable over a range of approximately 9.5-10 GHz,
giving added versatility to our fixed field portable DNP
system. In addition, a field adjustable Halbach permanent
magnet has also been employed as another means for matching
the electron spin resonance condition. Both portable setups
provide large signal enhancements and with improvements in
design and engineering, greater than 100-fold 1H
enhancements are feasible.},
keywords = {Equipment Design / Equipment Failure Analysis / Magnetic
Resonance Spectroscopy: instrumentation / Magnetic Resonance
Spectroscopy: methods / Microwaves / Reproducibility of
Results / Sensitivity and Specificity / J (WoSType)},
cin = {ICG-3},
ddc = {550},
cid = {I:(DE-Juel1)ICG-3-20090406},
pnm = {Terrestrische Umwelt},
pid = {G:(DE-Juel1)FUEK407},
shelfmark = {Biochemical Research Methods / Physics, Atomic, Molecular
$\&$ Chemical / Spectroscopy},
typ = {PUB:(DE-HGF)16},
pubmed = {pmid:18226943},
UT = {WOS:000254800600012},
doi = {10.1016/j.jmr.2008.01.004},
url = {https://juser.fz-juelich.de/record/61830},
}