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000061939 0247_ $$2DOI$$a10.1016/j.apsusc.2007.07.125
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000061939 084__ $$2WoS$$aChemistry, Physical
000061939 084__ $$2WoS$$aMaterials Science, Coatings & Films
000061939 084__ $$2WoS$$aPhysics, Applied
000061939 084__ $$2WoS$$aPhysics, Condensed Matter
000061939 1001_ $$0P:(DE-HGF)0$$aPedio, M.$$b0
000061939 245__ $$aGrowth of Pentaceneon Ag(111) surface: A NEXAFS study
000061939 260__ $$aAmsterdam$$bNorth-Holland$$c2007
000061939 300__ $$a103 - 107
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000061939 440_0 $$0573$$aApplied Surface Science$$v254$$x0169-4332$$y1
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000061939 520__ $$aThin films of pentacene (C22H14) have become widely used in the field of organic electronics. Here films of C22H14 of thickness ranging from submonolayer to multilayer were thermally deposited on Ag(1 1 1) surface. The determination of molecular geometry in pentacene films on Ag(1 1 1) studied by X-ray absorption at different stages of growth up to one monolayer is presented.XAS spectra at the C K-edge were collected as a function of the direction of the electric field at the surface. The different features of the spectra were assigned to resonances related to the various molecular unoccupied states by the comparison with the absorption coefficient of the pentacene gas phase. The transitions involving antibonding pi states show a pronounced angular dependence for all the measured coverages, from submonolayer to multilayer. The spectra analysis indicates a nearly planar chemisorption of the first pentacene layer with a tilt angle of 10 degrees. (C) 2007 Elsevier B.V. All rights reserved.
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000061939 65320 $$2Author$$apentacene
000061939 65320 $$2Author$$aAg(111)
000061939 65320 $$2Author$$apolymers and organic compounds
000061939 65320 $$2Author$$aelectron states at surfaces and interfaces
000061939 65320 $$2Author$$aX-ray absorption spectroscopy
000061939 65320 $$2Author$$aEXAFS
000061939 65320 $$2Author$$aNEXAFS
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000061939 65320 $$2Author$$athin film structure and morphology
000061939 650_7 $$2WoSType$$aJ
000061939 7001_ $$0P:(DE-HGF)0$$aDoyle, B.$$b1
000061939 7001_ $$0P:(DE-HGF)0$$aMahne, N.$$b2
000061939 7001_ $$0P:(DE-HGF)0$$aGiglia, A.$$b3
000061939 7001_ $$0P:(DE-HGF)0$$aBorgatti, F.$$b4
000061939 7001_ $$0P:(DE-HGF)0$$aNannarone, S.$$b5
000061939 7001_ $$0P:(DE-HGF)0$$aHenze, S. K. M.$$b6
000061939 7001_ $$0P:(DE-Juel1)VDB73384$$aTemirov, R.$$b7$$uFZJ
000061939 7001_ $$0P:(DE-Juel1)128791$$aTautz, F. S.$$b8$$uFZJ
000061939 7001_ $$0P:(DE-HGF)0$$aCasalis, L.$$b9
000061939 7001_ $$0P:(DE-HGF)0$$aHudej, R.$$b10
000061939 7001_ $$0P:(DE-HGF)0$$aDanisman, M.F.$$b11
000061939 7001_ $$0P:(DE-HGF)0$$aNickel, B.$$b12
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000061939 8567_ $$uhttp://dx.doi.org/10.1016/j.apsusc.2007.07.125
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