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@ARTICLE{Leroy:62080,
author = {Leroy, P. and Revil, A. and Kemna, A. and Cosenza, P. and
Ghorbani, A.},
title = {{C}omplex conductivity of water-saturated packs of glass
beads},
journal = {Journal of colloid and interface science},
volume = {321},
issn = {0021-9797},
address = {Amsterdam [u.a.]},
publisher = {Elsevier},
reportid = {PreJuSER-62080},
pages = {103 - 117},
year = {2008},
note = {Record converted from VDB: 12.11.2012},
abstract = {The low-frequency conductivity response of water-saturated
packs of glass beads reflects a combination of two
processes. One process corresponds to the polarization of
the mineral/water interface coating the surface of the
grains. The other process corresponds to the Maxwell-Wagner
polarization associated with accumulation of the electrical
charges in the pore space of the composite medium. A model
of low-frequency conductivity dispersion is proposed. This
model is connected to a triple-layer model of
electrochemical processes occurring at the surface of
silica. This model accounts for the partition of the
counterions between the Stern and the diffuse layers. The
polarization of the mineral/water interface is modeled by
the electrochemical polarization model of Schurr for a
spherical grain. We take into account also the DC surface
conductivity contribution of protons of the sorbed water and
the contribution of the diffuse layer. At the scale of a
macroscopic representative elementary volume of the porous
material, the electrochemical polarization of a single grain
is convoluted with the grain size distribution of the porous
material. Finally, the Maxwell-Wagner polarization is
modeled using the complex conductivity of a granular porous
medium obtained from the differential effective medium
theory. The predictions of this model agree well with
experimental data of spectral induced polarization. Two
peaks are observed at low frequencies in the spectrum of the
phase. The first peak corresponds to the distribution of the
size of the beads and the second peak is due to the
roughness of the grains.},
keywords = {J (WoSType)},
cin = {ICG-4},
ddc = {540},
cid = {I:(DE-Juel1)VDB793},
pnm = {Terrestrische Umwelt},
pid = {G:(DE-Juel1)FUEK407},
shelfmark = {Chemistry, Physical},
typ = {PUB:(DE-HGF)16},
pubmed = {pmid:18272167},
UT = {WOS:000254767200012},
doi = {10.1016/j.jcis.2007.12.031},
url = {https://juser.fz-juelich.de/record/62080},
}