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@ARTICLE{KiendlerScharr:6233,
author = {Kiendler-Scharr, A. and Zhang, Q. and Hohaus, Th. and
Kleist, E. and Mensah, A. and Mentel, T. F. and Spindler, C.
and Uerlings, R. and Tillmann, R. and Wildt, J.},
title = {{A}erosol {M}ass {S}pectrometric {F}eatures of {B}iogenic
{SOA}: {O}bservations from a {P}lant {C}hamber and in
{R}ural {A}tmospheric {E}nvironments},
journal = {Environmental Science $\&$ Technology},
volume = {43},
issn = {0013-936X},
address = {Columbus, Ohio},
publisher = {American Chemical Society},
reportid = {PreJuSER-6233},
pages = {8166 - 8172},
year = {2009},
note = {We gratefully acknowledge support by the European
Commission (IP-EUCAARI, Contract No. 036833-2). Q.Z. was
supported by the U.S. Department of Energy's Atmospheric
Science Program (Office of Science, BER), Grant No.
DE-FG02-08ER64627. We thank James Allan (U. Manchester) for
the AMS data analysis software and anonymous reviewers for
their constructive comments.},
abstract = {Secondary organic aerosol (SOA) is known to form from a
variety of anthropogenic and biogenic precursors. Current
estimates of global SOA production vary over 2 orders of
magnitude. Since no direct measurement technique for SOA
exists, quantifying SOA remains a challenge for atmospheric
studies. The identification of biogenic SOA (BSOA) based on
mass spectral signatures offers the possibility to derive
source information of organic aerosol (OA) with high time
resolution. Here we present data from simulation
experiments. The BSOA from tree emissions was characterized
with an Aerodyne quadrupole aerosol mass spectrometer
(Q-AMS). Collection efficiencies were close to 1, and
effective densities of the BSOA were found to be 1.3 +/- 0.1
g/cm(3). The mass spectra of SOA from different trees were
found to be highly similar. The average BSOA mass spectrum
from tree emissions is compared to a BSOA component spectrum
extracted from field data. It is shown that overall the
spectra agree well and that the mass spectral features of
BSOA are distinctively different from those of OA components
related to fresh fossil fuel and biomass combustions. The
simulation chamber mass spectrum may potentially be useful
for the identification and interpretation of biogenic SOA
components in ambient data sets.},
keywords = {Aerosols: analysis / Atmosphere: chemistry / Mass
Spectrometry / Organic Chemicals: analysis / Particle Size /
Time Factors / Trees: chemistry / Volatilization / Aerosols
(NLM Chemicals) / Organic Chemicals (NLM Chemicals) / J
(WoSType)},
cin = {ICG-2 / ICG-3},
ddc = {050},
cid = {I:(DE-Juel1)VDB791 / I:(DE-Juel1)ICG-3-20090406},
pnm = {Atmosphäre und Klima / Terrestrische Umwelt},
pid = {G:(DE-Juel1)FUEK406 / G:(DE-Juel1)FUEK407},
shelfmark = {Engineering, Environmental / Environmental Sciences},
typ = {PUB:(DE-HGF)16},
pubmed = {pmid:19924939},
UT = {WOS:000271106300033},
doi = {10.1021/es901420b},
url = {https://juser.fz-juelich.de/record/6233},
}