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@ARTICLE{VanderDonk:62554,
author = {Van der Donk, G. J. W. and Serra, J. M. and Meulenberg, W.
A.},
title = {{M}icroporous and mesoporous 8{YSZ} materials derived from
polymeric acetylacetone-modified precursors for inorganic
membrane applications},
journal = {Journal of non-crystalline solids},
volume = {354},
issn = {0022-3093},
address = {Amsterdam [u.a.]},
publisher = {Elsevier Science},
reportid = {PreJuSER-62554},
pages = {3723 - 3731},
year = {2008},
note = {Record converted from VDB: 12.11.2012},
abstract = {Both microporous and mesoporous $8\%$ mol-yttria-stabilized
zirconia (8YSZ) material can be prepared from the same 8YSZ
sols. Stable 8YSZ sols with particle sizes smaller than 10
nm were prepared by using acetylacetone as a precursor
modifier in combination with carboxylic acids. Nonanic and
caproic acids are preferred due to their higher stability in
combinations of highly concentrated sols. Cubic 8YSZ
microporous material can be prepared by using acetylacetone
as a precursor modifier with caproic acid as the catalyst.
These materials can be transformed into mesoporous material
composed of crystalline primary cubic YSZ nanoparticles by
simply mixing with structure-directing agents. Use of the
block copolymer F127 resulted in the largest specific
surface area of 100 m(2)/g. Thin 8YSZ layers of these sols
can be prepared on glass slips and on graded porous alumina
supports with thicknesses between 20 and 100 nm. (C) 2008
Elsevier B.V. All rights reserved.},
keywords = {J (WoSType)},
cin = {IEF-1},
ddc = {660},
cid = {I:(DE-Juel1)VDB809},
pnm = {Rationelle Energieumwandlung},
pid = {G:(DE-Juel1)FUEK402},
shelfmark = {Materials Science, Ceramics / Materials Science,
Multidisciplinary},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000258051500009},
doi = {10.1016/j.jnoncrysol.2008.03.048},
url = {https://juser.fz-juelich.de/record/62554},
}