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@ARTICLE{Sunarso:62565,
author = {Sunarso, J. and Baumann, S. and Serra, J. M. and
Meulenberg, W. A. and Liu, S. and Lin, Y.S. and Diniz da
Costa, J.C.},
title = {{M}ixed ionic-electronic conducting ({MIEC}) ceramic-based
membranes for oxygen separation},
journal = {Journal of membrane science},
volume = {320},
issn = {0376-7388},
address = {New York, NY [u.a.]},
publisher = {Elsevier},
reportid = {PreJuSER-62565},
pages = {13 - 41},
year = {2008},
note = {Record converted from VDB: 12.11.2012},
abstract = {Although Nernst observed ionic conduction of
zirconia-yttria solutions in 1899, the field of oxygen
separation research remained dormant. In the last 30 years,
research efforts by the scientific community intensified
significantly, stemming from the pioneering work of
Takahashi and co-workers, with the initial development of
mixed ionic-electronic conducting (MIEC) oxides. A large
number of MIEC compounds have been synthesized and
characterized since then, mainly based on perovskites
(ABO(3-delta) and A(2)BO(4 +/-delta)) and fluorites
(A(delta)B(1-delta)O(2-delta) and A(2 delta)B(2-2
delta)O(3)), or dual-phases by the introduction of metal or
ceramic elements. These compounds form dense ceramic
membranes, which exhibit significant oxygen ionic and
electronic conductivity at elevated temperatures. in turn,
this process allows for the ionic transport of oxygen from
air due to the differential partial pressure of oxygen
across the membrane, providing the driving force for oxygen
ion transport. As a result, defect-free synthesized
membranes deliver $100\%$ pure oxygen. Electrons involved in
the electrochemical oxidation and reduction of oxygen ions
and oxygen molecules respectively are transported in the
opposite direction, thus ensuring overall electrical
neutrality. Notably, the fundamental application of the
defect theory was deduced to a plethora of MIEC materials
over the last 30 years, providing the understanding of
electronic and ionic transport, in particular when dopants
are introduced to the compound of interest. As a
consequence, there are many special cases of ionic oxygen
transport limitation accompanied by phase changes, depending
upon the temperature and oxygen partial pressure operating
conditions. This paper aims at reviewing all the significant
and relevant contribution of the research community in this
area in the last three decades in conjunction with
theoretical principles. (C) 2008 Elsevier B.V. All rights
reserved.},
keywords = {J (WoSType)},
cin = {IEF-1},
ddc = {570},
cid = {I:(DE-Juel1)VDB809},
pnm = {Rationelle Energieumwandlung},
pid = {G:(DE-Juel1)FUEK402},
shelfmark = {Engineering, Chemical / Polymer Science},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000257834700003},
doi = {10.1016/j.memsci.2008.03.074},
url = {https://juser.fz-juelich.de/record/62565},
}